Facile Amine Formation by Intermolecular Catalytic Amidation of Carbon−Hydrogen Bonds

A simple copper-based catalytic system has been developed for the carbon−hydrogen amidation reaction. The copper−homoscorpionate complex TpBr3Cu(NCMe) catalyzes the transfer of the nitrene unit NTs (Ts = p-toluenesulfonyl) and its subsequent insertion into the sp3 C−H bonds of alkyl aromatic and cyc...

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Veröffentlicht in:	Journal of the American Chemical Society 2006-09, Vol.128 (36), p.11784-11791
Hauptverfasser:	Fructos, Manuel R, Trofimenko, Swiatoslaw, Díaz-Requejo, M. Mar, Pérez, Pedro J
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology General and physical chemistry
Online-Zugang:	Volltext
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