A 3D Canted Antiferromagnetic Porous Metal−Organic Framework with Anatase Topology through Assembly of an Analogue of Polyoxometalate
The unique porous metal−organic framework {KCo3(C6H4O7)(C6H5O7)(H2O)2·8H2O}8 (1), which exhibits an unprecedented infinite 3D (3,6)-connected decorated anatase net, has been obtained by hydrothermal reaction. Upon dehydration, the compound retains crystallinity and exhibits a type I N2 sorption isot...
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| Veröffentlicht in: | Journal of the American Chemical Society 2005-11, Vol.127 (47), p.16352-16353 |
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| container_issue | 47 |
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| container_title | Journal of the American Chemical Society |
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| creator | Xiang, Shengchang Wu, Xintao Zhang, Jianjun Fu, Ruibiao Hu, Shengmin Zhang, Xudong |
| description | The unique porous metal−organic framework {KCo3(C6H4O7)(C6H5O7)(H2O)2·8H2O}8 (1), which exhibits an unprecedented infinite 3D (3,6)-connected decorated anatase net, has been obtained by hydrothermal reaction. Upon dehydration, the compound retains crystallinity and exhibits a type I N2 sorption isotherm, characteristic of a microporous solid with apparent Langmuir surface area 939 m2/g and pore volume 0.31 cm3/g. Magnetic measurements for both 1 and dehydrated 1 show the spin-canted antiferromagnetic state below 5 K and a magnetic hysteresis loop at 2 K. Thus, dehydrated 1 represents the first metal−organic framework for which microporosity and a spin-canted antiferromagnetic state coexist, which demonstrates that the self-assembly of organo-polymetal clusters and metal ions can provide a potential route to magnetic porous metal−organic frameworks. |
| doi_str_mv | 10.1021/ja0546065 |
| format | Article |
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Upon dehydration, the compound retains crystallinity and exhibits a type I N2 sorption isotherm, characteristic of a microporous solid with apparent Langmuir surface area 939 m2/g and pore volume 0.31 cm3/g. Magnetic measurements for both 1 and dehydrated 1 show the spin-canted antiferromagnetic state below 5 K and a magnetic hysteresis loop at 2 K. Thus, dehydrated 1 represents the first metal−organic framework for which microporosity and a spin-canted antiferromagnetic state coexist, which demonstrates that the self-assembly of organo-polymetal clusters and metal ions can provide a potential route to magnetic porous metal−organic frameworks.</description><identifier>ISSN: 0002-7863</identifier><identifier>EISSN: 1520-5126</identifier><identifier>DOI: 10.1021/ja0546065</identifier><identifier>PMID: 16305195</identifier><identifier>CODEN: JACSAT</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Antiferromagnetics ; Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Exact sciences and technology ; Magnetic properties and materials ; Physics ; Studies of specific magnetic materials</subject><ispartof>Journal of the American Chemical Society, 2005-11, Vol.127 (47), p.16352-16353</ispartof><rights>Copyright © 2005 American Chemical Society</rights><rights>2006 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a343t-4c3872d47b659580a84633fef83c9749442b381c60588c837c8eff8cfcf2abf13</citedby><cites>FETCH-LOGICAL-a343t-4c3872d47b659580a84633fef83c9749442b381c60588c837c8eff8cfcf2abf13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ja0546065$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ja0546065$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=17310625$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/16305195$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Xiang, Shengchang</creatorcontrib><creatorcontrib>Wu, Xintao</creatorcontrib><creatorcontrib>Zhang, Jianjun</creatorcontrib><creatorcontrib>Fu, Ruibiao</creatorcontrib><creatorcontrib>Hu, Shengmin</creatorcontrib><creatorcontrib>Zhang, Xudong</creatorcontrib><title>A 3D Canted Antiferromagnetic Porous Metal−Organic Framework with Anatase Topology through Assembly of an Analogue of Polyoxometalate</title><title>Journal of the American Chemical Society</title><addtitle>J. Am. Chem. Soc</addtitle><description>The unique porous metal−organic framework {KCo3(C6H4O7)(C6H5O7)(H2O)2·8H2O}8 (1), which exhibits an unprecedented infinite 3D (3,6)-connected decorated anatase net, has been obtained by hydrothermal reaction. Upon dehydration, the compound retains crystallinity and exhibits a type I N2 sorption isotherm, characteristic of a microporous solid with apparent Langmuir surface area 939 m2/g and pore volume 0.31 cm3/g. Magnetic measurements for both 1 and dehydrated 1 show the spin-canted antiferromagnetic state below 5 K and a magnetic hysteresis loop at 2 K. Thus, dehydrated 1 represents the first metal−organic framework for which microporosity and a spin-canted antiferromagnetic state coexist, which demonstrates that the self-assembly of organo-polymetal clusters and metal ions can provide a potential route to magnetic porous metal−organic frameworks.</description><subject>Antiferromagnetics</subject><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Exact sciences and technology</subject><subject>Magnetic properties and materials</subject><subject>Physics</subject><subject>Studies of specific magnetic materials</subject><issn>0002-7863</issn><issn>1520-5126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNptkM9uEzEQhy1ERUPgwAsgX0DisMX_1zlGgQJSq_ZQzqtZZ5xu2F0H26uSJ4Azj8iT4KhRy4HTaGa--Vn-CHnF2Rlngr_fAtPKMKOfkBnXglWaC_OUzBhjoqqtkafkeUrb0iph-TNyyo1kmi_0jPxcUvmBrmDMuKbLMXceYwwDbEbMnaPXIYYp0UvM0P_59fsqbmAs4_MIA96F-I3edfm23EGGhPQm7EIfNnuab8vZpixSwqHt9zR4CuOBK-sJD-116PfhRxgOyZDxBTnx0Cd8eaxz8vX8483qc3Vx9enLanlRgVQyV8pJW4u1qlujF9oysMpI6dFb6Ra1WiglWmm5M0xb66ysnUXvrfPOC2g9l3Py9j53F8P3CVNuhi457HsYsfy0MdYKI4uyOXl3D7oYUorom13sBoj7hrPmYL15sF7Y18fQqR1w_UgeNRfgzRGA5KD3EUbXpUeulpwZ8Q8HLjXbMMUiLP3nwb_tq5dV</recordid><startdate>20051130</startdate><enddate>20051130</enddate><creator>Xiang, Shengchang</creator><creator>Wu, Xintao</creator><creator>Zhang, Jianjun</creator><creator>Fu, Ruibiao</creator><creator>Hu, Shengmin</creator><creator>Zhang, Xudong</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20051130</creationdate><title>A 3D Canted Antiferromagnetic Porous Metal−Organic Framework with Anatase Topology through Assembly of an Analogue of Polyoxometalate</title><author>Xiang, Shengchang ; Wu, Xintao ; Zhang, Jianjun ; Fu, Ruibiao ; Hu, Shengmin ; Zhang, Xudong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a343t-4c3872d47b659580a84633fef83c9749442b381c60588c837c8eff8cfcf2abf13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Antiferromagnetics</topic><topic>Condensed matter: electronic structure, electrical, magnetic, and optical properties</topic><topic>Exact sciences and technology</topic><topic>Magnetic properties and materials</topic><topic>Physics</topic><topic>Studies of specific magnetic materials</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xiang, Shengchang</creatorcontrib><creatorcontrib>Wu, Xintao</creatorcontrib><creatorcontrib>Zhang, Jianjun</creatorcontrib><creatorcontrib>Fu, Ruibiao</creatorcontrib><creatorcontrib>Hu, Shengmin</creatorcontrib><creatorcontrib>Zhang, Xudong</creatorcontrib><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of the American Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xiang, Shengchang</au><au>Wu, Xintao</au><au>Zhang, Jianjun</au><au>Fu, Ruibiao</au><au>Hu, Shengmin</au><au>Zhang, Xudong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A 3D Canted Antiferromagnetic Porous Metal−Organic Framework with Anatase Topology through Assembly of an Analogue of Polyoxometalate</atitle><jtitle>Journal of the American Chemical Society</jtitle><addtitle>J. Am. Chem. Soc</addtitle><date>2005-11-30</date><risdate>2005</risdate><volume>127</volume><issue>47</issue><spage>16352</spage><epage>16353</epage><pages>16352-16353</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><coden>JACSAT</coden><abstract>The unique porous metal−organic framework {KCo3(C6H4O7)(C6H5O7)(H2O)2·8H2O}8 (1), which exhibits an unprecedented infinite 3D (3,6)-connected decorated anatase net, has been obtained by hydrothermal reaction. Upon dehydration, the compound retains crystallinity and exhibits a type I N2 sorption isotherm, characteristic of a microporous solid with apparent Langmuir surface area 939 m2/g and pore volume 0.31 cm3/g. Magnetic measurements for both 1 and dehydrated 1 show the spin-canted antiferromagnetic state below 5 K and a magnetic hysteresis loop at 2 K. Thus, dehydrated 1 represents the first metal−organic framework for which microporosity and a spin-canted antiferromagnetic state coexist, which demonstrates that the self-assembly of organo-polymetal clusters and metal ions can provide a potential route to magnetic porous metal−organic frameworks.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>16305195</pmid><doi>10.1021/ja0546065</doi><tpages>2</tpages></addata></record> |
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| subjects | Antiferromagnetics Condensed matter: electronic structure, electrical, magnetic, and optical properties Exact sciences and technology Magnetic properties and materials Physics Studies of specific magnetic materials |
| title | A 3D Canted Antiferromagnetic Porous Metal−Organic Framework with Anatase Topology through Assembly of an Analogue of Polyoxometalate |
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