Consistent Approach to Adsorption Thermodynamics on Heterogeneous Surfaces Using Different Empirical Energy Distribution Models

Adsorption on heterogeneous surfaces with three basic energy distribution models (uniform model, exponential model, and normal-like model) is studied. Exact analytical solutions of the adsorption isotherms and the heats of adsorption are derived for the uniform and exponential models, and, with thes...

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Veröffentlicht in:	Langmuir 2006-09, Vol.22 (19), p.8063-8070
Hauptverfasser:	Xia, Xinyu, Litvinov, Sergey, Muhler, Martin
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Chemistry Exact sciences and technology General and physical chemistry Surface physical chemistry Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Online-Zugang:	Volltext
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