A Multisite Molecular Mechanism for Baeyer-Villiger Oxidations on Solid Catalysts Using Environmentally Friendly H2O2 as Oxidant

The molecular mechanism of the Baeyer–Villiger oxidation of cyclohexanone with hydrogen peroxide catalyzed by the Sn‐beta zeolite has been investigated by combining molecular mechanics, quantum‐chemical calculations, spectroscopic, and kinetic techniques. A theoretical study of the location of Sn in...

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Veröffentlicht in:	Chemistry : a European journal 2005-11, Vol.11 (23), p.6905-6915
Hauptverfasser:	Boronat, Mercedes, Corma, Avelino, Renz, Michael, Sastre, Germán, Viruela, Pedro M.
Format:	Artikel
Sprache:	eng
Schlagworte:	Baeyer-Villiger reactions density functional calculations kinetics Lewis acids tin zeolites
Online-Zugang:	Volltext
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