Glycosyl Disulfides:  Novel Glycosylating Reagents with Flexible Aglycon Alteration

Glycosyl disulfides have been shown for the first time to be effective glycosyl donors. Glucosylation and galactosylation of a panel of representative alcohol acceptors allowed the formation of 28 simple glycosides, disaccharides, and glycoamino acids in yields of up to 90%. As well as providing a n...

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Veröffentlicht in:	Journal of organic chemistry 2005-11, Vol.70 (24), p.9740-9754
Hauptverfasser:	Grayson, Elizabeth J, Ward, Sarah J, Hall, Alison L, Rendle, Phillip M, Gamblin, David P, Batsanov, Andrei S, Davis, Benjamin G
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbohydrates with 4, 5, 6, ... C atoms, dissacharides and oligosaccharides Carbohydrates. Nucleosides and nucleotides Chemistry Disulfides - chemical synthesis Disulfides - chemistry Doxorubicin - analogs & derivatives Doxorubicin - chemical synthesis Doxorubicin - chemistry Exact sciences and technology Glycosides - chemical synthesis Glycosides - chemistry Glycosylation Molecular Conformation Organic chemistry Preparations and properties
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