Glycosyl trichloroacetylcarbamate: a new glycosyl donor for O-glycosylation
Glycosyl trichloroacetylcarbamates, readily obtained by reacting 1-hydroxy sugars with trichloroacetylisocyanate, have been found as excellent glycosyl donors, and the corresponding O-glycosides are formed in good to excellent yields with a fairly good degree of selectivity.
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Veröffentlicht in: | Carbohydrate research 2005-12, Vol.340 (17), p.2688-2692 |
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container_title | Carbohydrate research |
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creator | Jayakanthan, K. Vankar, Yashwant D. |
description | Glycosyl trichloroacetylcarbamates, readily obtained by reacting 1-hydroxy sugars with trichloroacetylisocyanate, have been found as excellent glycosyl donors, and the corresponding
O-glycosides are formed in good to excellent yields with a fairly good degree of selectivity. |
doi_str_mv | 10.1016/j.carres.2005.07.024 |
format | Article |
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O-glycosides are formed in good to excellent yields with a fairly good degree of selectivity.</description><subject>Carbamates - chemistry</subject><subject>Carbohydrate Conformation</subject><subject>Glycosides - chemical synthesis</subject><subject>Glycosides - chemistry</subject><subject>Glycosylation</subject><subject>Indicators and Reagents</subject><subject>Kinetics</subject><subject>Models, Molecular</subject><subject>O-glycosylation</subject><subject>Sugar Alcohols - chemistry</subject><subject>Trichloroacetylcarbamate</subject><subject>Trichloroacetylisocyanate</subject><subject>Trimethylsilyltriflate</subject><issn>0008-6215</issn><issn>1873-426X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNp9kMFKw0AQhhdRbK2-gUhO3hJnk81u4kGQolUs9KLgbZluJpqSZutuquTtTUmLNw_LsMM3_zAfY5ccIg5c3qwig86Rj2KANAIVQSyO2JhnKglFLN-P2RgAslDGPB2xM-9X_RekkqdsxPtmnKcwZi-zujPWd3XQusp81tZZNNR2dR--xDW2dBtg0NBP8HEAC9tYF5T9W4SHJraVbc7ZSYm1p4t9nbC3x4fX6VM4X8yep_fz0CQS2lCqFFEKpYRQmBiRKmMISpVlOZQoiwITkYmSClMYXooEUaUywzQHI5ZlDsmEXQ-5G2e_tuRbva68obrGhuzWa5llEIPcgWIAjbPeOyr1xlVrdJ3moHcS9UoPEvVOogale4n92NU-f7tcU_E3tLfWA3cDQP2V3xU57U1FjaGicmRaXdjq_w2_5D2GRQ</recordid><startdate>20051212</startdate><enddate>20051212</enddate><creator>Jayakanthan, K.</creator><creator>Vankar, Yashwant D.</creator><general>Elsevier Ltd</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20051212</creationdate><title>Glycosyl trichloroacetylcarbamate: a new glycosyl donor for O-glycosylation</title><author>Jayakanthan, K. ; Vankar, Yashwant D.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c360t-675aa6477447a3c457cce0f78890fa6dda3484fedcdc1f43aa7568a590c4bf903</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Carbamates - chemistry</topic><topic>Carbohydrate Conformation</topic><topic>Glycosides - chemical synthesis</topic><topic>Glycosides - chemistry</topic><topic>Glycosylation</topic><topic>Indicators and Reagents</topic><topic>Kinetics</topic><topic>Models, Molecular</topic><topic>O-glycosylation</topic><topic>Sugar Alcohols - chemistry</topic><topic>Trichloroacetylcarbamate</topic><topic>Trichloroacetylisocyanate</topic><topic>Trimethylsilyltriflate</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jayakanthan, K.</creatorcontrib><creatorcontrib>Vankar, Yashwant D.</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Carbohydrate research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jayakanthan, K.</au><au>Vankar, Yashwant D.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Glycosyl trichloroacetylcarbamate: a new glycosyl donor for O-glycosylation</atitle><jtitle>Carbohydrate research</jtitle><addtitle>Carbohydr Res</addtitle><date>2005-12-12</date><risdate>2005</risdate><volume>340</volume><issue>17</issue><spage>2688</spage><epage>2692</epage><pages>2688-2692</pages><issn>0008-6215</issn><eissn>1873-426X</eissn><abstract>Glycosyl trichloroacetylcarbamates, readily obtained by reacting 1-hydroxy sugars with trichloroacetylisocyanate, have been found as excellent glycosyl donors, and the corresponding
O-glycosides are formed in good to excellent yields with a fairly good degree of selectivity.</abstract><cop>Netherlands</cop><pub>Elsevier Ltd</pub><pmid>16212950</pmid><doi>10.1016/j.carres.2005.07.024</doi><tpages>5</tpages></addata></record> |
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subjects | Carbamates - chemistry Carbohydrate Conformation Glycosides - chemical synthesis Glycosides - chemistry Glycosylation Indicators and Reagents Kinetics Models, Molecular O-glycosylation Sugar Alcohols - chemistry Trichloroacetylcarbamate Trichloroacetylisocyanate Trimethylsilyltriflate |
title | Glycosyl trichloroacetylcarbamate: a new glycosyl donor for O-glycosylation |
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