Unusual Rate Enhancement of Bimolecular Dehydrocondensation To Form Amides at the Interface of Micelles of Fatty Acid Salts
Speeding up: A micelle–water interface acts as a suitable reaction field for dehydrocondensation. The coupling reaction of fatty acid salts with a triazine‐type amphiphilic dehydrocondensing agent in a micellar system (see picture) underwent up to 2000‐fold acceleration. The rate enhancement can be...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2005-11, Vol.44 (44), p.7254-7257 |
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| container_end_page | 7257 |
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| container_issue | 44 |
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| container_title | Angewandte Chemie International Edition |
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| creator | Kunishima, Munetaka Imada, Hiroko Kikuchi, Kanako Hioki, Kazuhito Nishida, Jin Tani, Shohei |
| description | Speeding up: A micelle–water interface acts as a suitable reaction field for dehydrocondensation. The coupling reaction of fatty acid salts with a triazine‐type amphiphilic dehydrocondensing agent in a micellar system (see picture) underwent up to 2000‐fold acceleration. The rate enhancement can be attributed to the higher local concentration and preorientation of the reactants in the micelles. |
| doi_str_mv | 10.1002/anie.200502594 |
| format | Article |
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| source | MEDLINE; Access via Wiley Online Library |
| subjects | amides Amides - chemical synthesis Amides - chemistry Binding, Competitive condensation Fatty Acids - chemistry Kinetics Micelles Molecular Structure Surface Properties triazines Triazines - chemistry |
| title | Unusual Rate Enhancement of Bimolecular Dehydrocondensation To Form Amides at the Interface of Micelles of Fatty Acid Salts |
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