Enantioselective Transfer Aminoallylation: Synthesis of Optically Active Homoallylic Primary Amines
A camphorquinone-derived chiral homoallylic amine was found to react with various aldehydes via imine formation and asymmetric 2-azonia-Cope rearrangement to give optically active homoallylic primary amines. A practical level of enantioselectivity with high functional group tolerance has been attain...
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| Veröffentlicht in: | Journal of the American Chemical Society 2006-08, Vol.128 (34), p.11038-11039 |
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| container_end_page | 11039 |
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| container_issue | 34 |
| container_start_page | 11038 |
| container_title | Journal of the American Chemical Society |
| container_volume | 128 |
| creator | Sugiura, Masaharu Mori, Chieko Kobayashi, Shū |
| description | A camphorquinone-derived chiral homoallylic amine was found to react with various aldehydes via imine formation and asymmetric 2-azonia-Cope rearrangement to give optically active homoallylic primary amines. A practical level of enantioselectivity with high functional group tolerance has been attained in this transformation. |
| doi_str_mv | 10.1021/ja064106r |
| format | Article |
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Am. Chem. Soc</addtitle><description>A camphorquinone-derived chiral homoallylic amine was found to react with various aldehydes via imine formation and asymmetric 2-azonia-Cope rearrangement to give optically active homoallylic primary amines. 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| identifier | ISSN: 0002-7863 |
| ispartof | Journal of the American Chemical Society, 2006-08, Vol.128 (34), p.11038-11039 |
| issn | 0002-7863 1520-5126 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_68775048 |
| source | MEDLINE; ACS Publications |
| subjects | Amines - chemistry Chemistry Exact sciences and technology General and physical chemistry Stereoisomerism |
| title | Enantioselective Transfer Aminoallylation: Synthesis of Optically Active Homoallylic Primary Amines |
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