Synthetic Utilization of Polynitroaromatic Compounds. 3. Preparation of Substituted Dibenz[b,f][1,4]oxazepine-11(10H)-ones from 2,4,6-Trinitrobenzoic Acid via Nucleophilic Displacement of Nitro Groups

1,3-Dinitrodibenz[b,f][1,4]oxazepin-11(10H)-one, prepared by intramolecular displacement of nitro group in N-(2-hydroxyphenyl)-2,4,6-trinitrobenzamide, reacts with O- and S-nucleophiles to yield the products of mono- or bis-substitution of the nitro groups. The nitro group in position 3 is displaced...

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Veröffentlicht in:	Journal of organic chemistry 2005-11, Vol.70 (23), p.9371-9376
Hauptverfasser:	Samet, Alexander V, Marshalkin, Victor N, Kislyi, Konstantine A, Chernysheva, Natalya B, Strelenko, Yuri A, Semenov, Victor V
Format:	Artikel
Sprache:	eng
Schlagworte:	Dibenzoxazepines - chemical synthesis Dibenzoxazepines - chemistry Molecular Structure Nitro Compounds - chemistry
Online-Zugang:	Volltext
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