pi-Face donor properties of N-heterocyclic carbenes

pi-Face donor properties of N-heterocyclic carbenes

The donor properties of aryl substituted N-heterocyclic carbenes are characterized by lone pair donation from the carbene carbon and, as is shown here, by donation of electron density of the aromatic pi-face of the NHC aryl groups towards the metal.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2005-11 (43), p.5417-5419
Hauptverfasser: Süssner, Marcus, Plenio, Herbert
Format: Artikel
Sprache:eng
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Zusammenfassung:The donor properties of aryl substituted N-heterocyclic carbenes are characterized by lone pair donation from the carbene carbon and, as is shown here, by donation of electron density of the aromatic pi-face of the NHC aryl groups towards the metal.
ISSN:1359-7345
1364-548X
DOI:10.1039/b512008j