Acetophenone derivatives and sesquiterpene from Euphorbia ebracteolata

Abstract Two new acetophenone derivatives and a new sesquiterpene, along with four known acetophenone compounds, were isolated from the roots of EUPHORBIA EBRACTEOLATA. The structures of the new compounds were identified as 2,2′,4,4′-tetrahydroxy-6,6′-dimethoxy-3,3′-dimethyl-7,5′-bisacetophenone, 2,...

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Veröffentlicht in:Planta medica 2005-10, Vol.71 (10), p.979-982
Hauptverfasser: Yin, Z.Q, Fan, C.L, Ye, W.C, Jiang, R.W, Che, C.T, Mak, T.C.W, Zhao, S.X, Yao, X.S
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container_end_page 982
container_issue 10
container_start_page 979
container_title Planta medica
container_volume 71
creator Yin, Z.Q
Fan, C.L
Ye, W.C
Jiang, R.W
Che, C.T
Mak, T.C.W
Zhao, S.X
Yao, X.S
description Abstract Two new acetophenone derivatives and a new sesquiterpene, along with four known acetophenone compounds, were isolated from the roots of EUPHORBIA EBRACTEOLATA. The structures of the new compounds were identified as 2,2′,4,4′-tetrahydroxy-6,6′-dimethoxy-3,3′-dimethyl-7,5′-bisacetophenone, 2,4-dihydroxy-6-methoxy-3-methylacetophenone 4-O-α-L-arabinofuranosyl-(1→6)-β-D-glucopyranoside and decahydro-1a,4a,7,7-tetramethyl-1H-cycloprop[E]azulene-2,5-diol (1aR,2R,4aS,5S,7aR,7bR) using 1D and 2D NMR spectroscopy and X-ray crystallography.
doi_str_mv 10.1055/s-2005-871301
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The structures of the new compounds were identified as 2,2′,4,4′-tetrahydroxy-6,6′-dimethoxy-3,3′-dimethyl-7,5′-bisacetophenone, 2,4-dihydroxy-6-methoxy-3-methylacetophenone 4-O-α-L-arabinofuranosyl-(1→6)-β-D-glucopyranoside and decahydro-1a,4a,7,7-tetramethyl-1H-cycloprop[E]azulene-2,5-diol (1aR,2R,4aS,5S,7aR,7bR) using 1D and 2D NMR spectroscopy and X-ray crystallography.</description><subject>acetohenone</subject><subject>Acetophenones - chemistry</subject><subject>Biological and medical sciences</subject><subject>bisacetophenone</subject><subject>chemical structure</subject><subject>Crystallography, X-Ray</subject><subject>Euphorbia</subject><subject>Euphorbia ebracterolata</subject><subject>Euphorbiaceae</subject><subject>General pharmacology</subject><subject>glucopyranoside</subject><subject>Humans</subject><subject>ketones</subject><subject>Letter</subject><subject>Medical sciences</subject><subject>medicinal plants</subject><subject>methylacetophenone</subject><subject>Pharmacognosy. Homeopathy. Health food</subject><subject>Pharmacology. Drug treatments</subject><subject>Phytotherapy</subject><subject>plant biochemistry</subject><subject>plant extracts</subject><subject>Plant Extracts - chemistry</subject><subject>Plant Roots</subject><subject>Sesquiterpenes - chemistry</subject><subject>sesquiterpenoids</subject><subject>spectral analysis</subject><subject>stereochemistry</subject><subject>traditional medicine</subject><subject>X-ray diffraction</subject><issn>0032-0943</issn><issn>1439-0221</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNp90U1P3DAQBmALtYKFcuRacml7aeg4jr-OCEFbCamHwtkaO5NuUBIHO0Hqv29Wu4hbT3OYR6808zJ2weGKg5TfclkByNJoLoAfsQ2vhS2hqvg7tgEQVQm2FifsNOcnAF5bgGN2wlUlayP0ht1dB5rjtKUxjlQ0lLoXnLsXygWOTZEpPy_dTGmiddumOBS3y7SNyXdYkE8YZoo9zviBvW-xz3R-mGfs8e724eZHef_r-8-b6_syCK3mUjYoA7dBaW_Rc9UqNGSJW-2NbrlCaUjjekELgL5F2ZCplEbbeBvAc3HGvuxzpxSfF8qzG7ocqO9xpLhkpzXXYLU0q_z8X6mMFtrALvLjAS5-oMZNqRsw_XWvP1rBpwPAHLBvE46hy29OV1oYa1f3de_mbUcDuae4pHF9huPgdlW57HZVuX1VK7_c8xajwz9pjXz8XcFuB7UynIt_RVSMyw</recordid><startdate>20051001</startdate><enddate>20051001</enddate><creator>Yin, Z.Q</creator><creator>Fan, C.L</creator><creator>Ye, W.C</creator><creator>Jiang, R.W</creator><creator>Che, C.T</creator><creator>Mak, T.C.W</creator><creator>Zhao, S.X</creator><creator>Yao, X.S</creator><general>Thieme</general><scope>FBQ</scope><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>7X8</scope></search><sort><creationdate>20051001</creationdate><title>Acetophenone derivatives and sesquiterpene from Euphorbia ebracteolata</title><author>Yin, Z.Q ; Fan, C.L ; Ye, W.C ; Jiang, R.W ; Che, C.T ; Mak, T.C.W ; Zhao, S.X ; Yao, X.S</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c376t-5da5c19c67b9ab16f6a8e9e197b87f16a58e7a439f00abfa5de8267a9db9c0b13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>acetohenone</topic><topic>Acetophenones - chemistry</topic><topic>Biological and medical sciences</topic><topic>bisacetophenone</topic><topic>chemical structure</topic><topic>Crystallography, X-Ray</topic><topic>Euphorbia</topic><topic>Euphorbia ebracterolata</topic><topic>Euphorbiaceae</topic><topic>General pharmacology</topic><topic>glucopyranoside</topic><topic>Humans</topic><topic>ketones</topic><topic>Letter</topic><topic>Medical sciences</topic><topic>medicinal plants</topic><topic>methylacetophenone</topic><topic>Pharmacognosy. Homeopathy. Health food</topic><topic>Pharmacology. 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subjects acetohenone
Acetophenones - chemistry
Biological and medical sciences
bisacetophenone
chemical structure
Crystallography, X-Ray
Euphorbia
Euphorbia ebracterolata
Euphorbiaceae
General pharmacology
glucopyranoside
Humans
ketones
Letter
Medical sciences
medicinal plants
methylacetophenone
Pharmacognosy. Homeopathy. Health food
Pharmacology. Drug treatments
Phytotherapy
plant biochemistry
plant extracts
Plant Extracts - chemistry
Plant Roots
Sesquiterpenes - chemistry
sesquiterpenoids
spectral analysis
stereochemistry
traditional medicine
X-ray diffraction
title Acetophenone derivatives and sesquiterpene from Euphorbia ebracteolata
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