A Simple Route to Difluorocarbene and Perfluoroalkylidene Complexes of Iridium
Primary perfluoroalkyl compounds of iridium undergo facile two-electron reduction to afford a simple route to difluorocarbene and perfluoroalkylidene complexes, two of which have been crystallographically characterized. Low-temperature protonation reactions illustrate that the thermodynamic site of...
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| Veröffentlicht in: | Journal of the American Chemical Society 2005-11, Vol.127 (43), p.15020-15021 |
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| container_end_page | 15021 |
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| container_issue | 43 |
| container_start_page | 15020 |
| container_title | Journal of the American Chemical Society |
| container_volume | 127 |
| creator | Hughes, Russell P Laritchev, Roman B Yuan, Jian Golen, James A Rucker, Adam N Rheingold, Arnold L |
| description | Primary perfluoroalkyl compounds of iridium undergo facile two-electron reduction to afford a simple route to difluorocarbene and perfluoroalkylidene complexes, two of which have been crystallographically characterized. Low-temperature protonation reactions illustrate that the thermodynamic site of protonation depends on the nature of the fluorinated carbene; the difluorocarbene complex undergoes protonation at iridium, while its perfluoroethylidene congener undergoes protonation at carbon. |
| doi_str_mv | 10.1021/ja055166k |
| format | Article |
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Low-temperature protonation reactions illustrate that the thermodynamic site of protonation depends on the nature of the fluorinated carbene; the difluorocarbene complex undergoes protonation at iridium, while its perfluoroethylidene congener undergoes protonation at carbon.</description><identifier>ISSN: 0002-7863</identifier><identifier>EISSN: 1520-5126</identifier><identifier>DOI: 10.1021/ja055166k</identifier><identifier>PMID: 16248629</identifier><identifier>CODEN: JACSAT</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Chemistry ; Condensed matter: structure, mechanical and thermal properties ; Exact sciences and technology ; Organic chemistry ; Organic compounds ; Organometalloidal and organometallic compounds ; Physics ; Preparations and properties ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids ; Transition metals derivatives</subject><ispartof>Journal of the American Chemical Society, 2005-11, Vol.127 (43), p.15020-15021</ispartof><rights>Copyright © 2005 American Chemical Society</rights><rights>2006 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a447t-47eac818296df9bc4e7b0706d6de8a62ab9f30bac28cd5b791205e3f2e49f8cb3</citedby><cites>FETCH-LOGICAL-a447t-47eac818296df9bc4e7b0706d6de8a62ab9f30bac28cd5b791205e3f2e49f8cb3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ja055166k$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ja055166k$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2756,27067,27915,27916,56729,56779</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=17219394$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/16248629$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Hughes, Russell P</creatorcontrib><creatorcontrib>Laritchev, Roman B</creatorcontrib><creatorcontrib>Yuan, Jian</creatorcontrib><creatorcontrib>Golen, James A</creatorcontrib><creatorcontrib>Rucker, Adam N</creatorcontrib><creatorcontrib>Rheingold, Arnold L</creatorcontrib><title>A Simple Route to Difluorocarbene and Perfluoroalkylidene Complexes of Iridium</title><title>Journal of the American Chemical Society</title><addtitle>J. Am. Chem. Soc</addtitle><description>Primary perfluoroalkyl compounds of iridium undergo facile two-electron reduction to afford a simple route to difluorocarbene and perfluoroalkylidene complexes, two of which have been crystallographically characterized. Low-temperature protonation reactions illustrate that the thermodynamic site of protonation depends on the nature of the fluorinated carbene; the difluorocarbene complex undergoes protonation at iridium, while its perfluoroethylidene congener undergoes protonation at carbon.</description><subject>Chemistry</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Exact sciences and technology</subject><subject>Organic chemistry</subject><subject>Organic compounds</subject><subject>Organometalloidal and organometallic compounds</subject><subject>Physics</subject><subject>Preparations and properties</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><subject>Transition metals derivatives</subject><issn>0002-7863</issn><issn>1520-5126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNpt0M1O3DAUBWALgWCALvoCVTZUYhFqO4l_lnSgLRJqoQNiad0415JnkniwEwnevhnNiNl0Zfn689HVIeQzo1eMcvZtCbSqmBCrAzJjFad5xbg4JDNKKc-lEsUJOU1pOV1LrtgxOWGCl0pwPSO_r7OF79YtZn_DOGA2hOzGu3YMMViINfaYQd9kDxi3Q2hX761vNvN52Px7w5QFl91F3_ixOydHDtqEn3bnGXn-cfs0_5Xf__l5N7--z6Es5ZCXEsEqprgWjdO1LVHWVFLRiAYVCA61dgWtwXJlm6qWmnFaYeE4ltopWxdn5Os2dx3D64hpMJ1PFtsWegxjMkLJgiuqJ3i5hTaGlCI6s46-g_huGDWb8sxHeZP9sgsd6w6bvdy1NYGLHYBkoXUReuvT3knOdKHLyeVb59OAbx_vEFdGyEJW5ulhYeaV_r5g4tG87HPBJrMMY-yn7v6z4D8gFZI9</recordid><startdate>20051102</startdate><enddate>20051102</enddate><creator>Hughes, Russell P</creator><creator>Laritchev, Roman B</creator><creator>Yuan, Jian</creator><creator>Golen, James A</creator><creator>Rucker, Adam N</creator><creator>Rheingold, Arnold L</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20051102</creationdate><title>A Simple Route to Difluorocarbene and Perfluoroalkylidene Complexes of Iridium</title><author>Hughes, Russell P ; Laritchev, Roman B ; Yuan, Jian ; Golen, James A ; Rucker, Adam N ; Rheingold, Arnold L</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a447t-47eac818296df9bc4e7b0706d6de8a62ab9f30bac28cd5b791205e3f2e49f8cb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Chemistry</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Exact sciences and technology</topic><topic>Organic chemistry</topic><topic>Organic compounds</topic><topic>Organometalloidal and organometallic compounds</topic><topic>Physics</topic><topic>Preparations and properties</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><topic>Transition metals derivatives</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hughes, Russell P</creatorcontrib><creatorcontrib>Laritchev, Roman B</creatorcontrib><creatorcontrib>Yuan, Jian</creatorcontrib><creatorcontrib>Golen, James A</creatorcontrib><creatorcontrib>Rucker, Adam N</creatorcontrib><creatorcontrib>Rheingold, Arnold L</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of the American Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hughes, Russell P</au><au>Laritchev, Roman B</au><au>Yuan, Jian</au><au>Golen, James A</au><au>Rucker, Adam N</au><au>Rheingold, Arnold L</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Simple Route to Difluorocarbene and Perfluoroalkylidene Complexes of Iridium</atitle><jtitle>Journal of the American Chemical Society</jtitle><addtitle>J. Am. Chem. Soc</addtitle><date>2005-11-02</date><risdate>2005</risdate><volume>127</volume><issue>43</issue><spage>15020</spage><epage>15021</epage><pages>15020-15021</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><coden>JACSAT</coden><abstract>Primary perfluoroalkyl compounds of iridium undergo facile two-electron reduction to afford a simple route to difluorocarbene and perfluoroalkylidene complexes, two of which have been crystallographically characterized. Low-temperature protonation reactions illustrate that the thermodynamic site of protonation depends on the nature of the fluorinated carbene; the difluorocarbene complex undergoes protonation at iridium, while its perfluoroethylidene congener undergoes protonation at carbon.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>16248629</pmid><doi>10.1021/ja055166k</doi><tpages>2</tpages></addata></record> |
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| source | ACS Publications |
| subjects | Chemistry Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Organic chemistry Organic compounds Organometalloidal and organometallic compounds Physics Preparations and properties Structure of solids and liquids crystallography Structure of specific crystalline solids Transition metals derivatives |
| title | A Simple Route to Difluorocarbene and Perfluoroalkylidene Complexes of Iridium |
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