Long-Range Electronic Coupling of MM Quadruple Bonds (M = Mo or W) via a 2,6-Azulenedicarboxylate Bridge

The preparation of 2,6-azulenedicarboxylic acid (I) from its diester, 2-CO2 t Bu-6-CO2-C10H6 (II), is reported together with the crystal and molecular structure of the ester, II. From the reactions between the dicarboxylic acid I and the MM quadruply bonded complexes M2(O2C t Bu)4, where M = Mo or W...

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Veröffentlicht in:	Journal of the American Chemical Society 2005-11, Vol.127 (43), p.15182-15190
Hauptverfasser:	Barybin, Mikhail V, Chisholm, Malcolm H, Dalal, Naresh S, Holovics, Thomas H, Patmore, Nathan J, Robinson, Randall E, Zipse, David J
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Condensed matter: structure, mechanical and thermal properties Coordination compounds Exact sciences and technology Inorganic chemistry and origins of life Inorganic compounds Metal complexes Physics Preparations and properties Structure of solids and liquids crystallography Structure of specific crystalline solids
Online-Zugang:	Volltext
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