The F/Ph Rearrangement Reaction of [(Ph3P)3RhF], the Fluoride Congener of Wilkinson's Catalyst

The fluoride congener of Wilkinson's catalyst, [(Ph3P)3RhF] (1), has been synthesized and fully characterized. Unlike Wilkinson's catalyst, 1 easily activates the inert C−Cl bond of ArCl (Ar = Ph, p-tolyl) under mild conditions (3 h at 80 °C) to produce trans-[(Ph3P)2Rh(Ph2PF)(Cl)] (2) and...

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Veröffentlicht in:	Journal of the American Chemical Society 2005-11, Vol.127 (43), p.15304-15321
Hauptverfasser:	Macgregor, Stuart A, Roe, D. Christopher, Marshall, William J, Bloch, Karen M, Bakhmutov, Vladimir I, Grushin, Vladimir V
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Condensed matter: structure, mechanical and thermal properties Coordination compounds Exact sciences and technology Inorganic chemistry and origins of life Inorganic compounds Metal complexes Physics Preparations and properties Structure of solids and liquids crystallography Structure of specific crystalline solids
Online-Zugang:	Volltext
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