[Co2(ppca)2(H2O)(V4O12)0.5]: A Framework Material Exhibiting Reversible Shrinkage and Expansion through a Single-Crystal-to-Single-Crystal Transformation Involving a Change in the Cobalt Coordination Environment

Shrinkage factor: The ligand ppca (4‐(pyridin‐4‐yl)pyridine‐2‐carboxylic acid) has enabled the synthesis of a new 3D framework material, [{[Co2(ppca)2(H2O)(V4O12)0.5]⋅3.62 H2O}n], which exhibits so‐called “dynamic structural changes”. Temperature changes lead to the reversible removal of guest molec...

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Veröffentlicht in:	Angewandte Chemie International Edition 2005-10, Vol.44 (41), p.6673-6677
Hauptverfasser:	Chen, Chun-Long, Goforth, Andrea M., Smith, Mark D., Su, Cheng-Yong, zur Loye, Hans-Conrad
Format:	Artikel
Sprache:	eng
Schlagworte:	cobalt dynamic structural changes ligand design microporous materials vanadium
Online-Zugang:	Volltext
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