Postmetallocene Lanthanide-Hydrido Chemistry: A New Family of Complexes [{Ln{(Me3Si)2NC(NiPr)2}2(μ-H)}2] (Ln=Y, Nd, Sm, Gd, Yb) Supported by Guanidinate Ligands-Synthesis, Structure, and Catalytic Activity in Olefin Polymerization

The new family of Lewis base free hydrido complexes of rare‐earth metals supported by guanidinate ligands [{Ln{(Me3Si)2NC(NiPr)2}2(μ‐H)}2] (Ln=Y, Nd, Sm, Gd, Yb) was synthesized and structurally characterized. Single‐crystal X‐ray and solution NMR studies revealed that these complexes are dimeric in...

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Veröffentlicht in:	Chemistry : a European journal 2006-07, Vol.12 (20), p.5320-5327
Hauptverfasser:	Trifonov, Alexander A., Skvortsov, Grigorii G., Lyubov, Dmitrii M., Skorodumova, Nina A., Fukin, Georgii K., Baranov, Evgenii V., Glushakova, Valentina N.
Format:	Artikel
Sprache:	eng
Schlagworte:	guanidinate ligands homogeneous catalysis hydrides lanthanides polymerization
Online-Zugang:	Volltext
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