Electrophilic Aromatic Nitration:  Understanding Its Mechanism and Substituent Effects

Theoretical calculations and gas-phase mass spectrometric studies were performed for the reaction of the naked (NO2 +) and monosolvated (CH3NO2·NO2 +) nitronium ion with several monosubstituted aromatic compounds. From these studies, we propose a general model for regioselectivity based on the singl...

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Veröffentlicht in:	Journal of organic chemistry 2006-08, Vol.71 (16), p.6192-6203
Hauptverfasser:	Queiroz, Jorge Freire de, Carneiro, José Walkimar de M, Sabino, Adão A, Sparrapan, Regina, Eberlin, Marcos N, Esteves, Pierre M
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Kinetics and mechanisms Organic chemistry Reactivity and mechanisms
Online-Zugang:	Volltext
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