Manganese (IV) oxide-catalyzed electrophilic diamination of electron-deficient alkenes provides an easy synthesis of α,β-diamino acid and ketone derivatives for peptidomimetic studies

:  Manganese (IV) oxide was found to catalyze the diamination reaction of α,β‐unsaturated esters and ketones with N,N‐dichloro‐p‐toluenesulfonamide and acetonitrile as the halogen and nitrogen sources. The reaction is convenient to be conducted by simply mixing three reactants in the presence of man...

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Veröffentlicht in:	The journal of peptide research 2005-11, Vol.66 (5), p.249-254
Hauptverfasser:	Timmons, C., Mcpherson, L.M., Chen, D., Wei, H.-X., Li, G.
Format:	Artikel
Sprache:	eng
Schlagworte:	alkene addition Alkenes - chemistry Catalysis Combinatorial Chemistry Techniques diamine Diamines - chemistry diamino acid Esters - chemistry imidazoline Ketones - chemical synthesis Ketones - chemistry manganese (IV) oxide Manganese Compounds - chemistry Molecular Structure Oxides - chemistry
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