Functionalization of Zeolite ZSM-5 by Hydrosilylation and Acetone Coupling:  Synthesis, MAS NMR, and Theory

We report a two-step postsynthetic functionalization reaction of zeolite HZSM-5 that proceeds with high selectivity at room temperature. In the first step the framework acid sites of the zeolite are reacted with phenylsilane to replace the acidic proton with a hydrosilyl (−SiH3) group covalently lin...

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Veröffentlicht in:The journal of physical chemistry. B 2006-08, Vol.110 (30), p.14598-14603
Hauptverfasser: Abubakar, Saifudin M, Lee, Jeffrey C, Marcus, David M, Ehresmann, Justin O, Haw, James F
Format: Artikel
Sprache:eng
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