Highly Enantioselective sec-Alkyl Sulfatase Activity of the Marine Planctomycete Rhodopirellula baltica Shows Retention of Configuration

Hydrolytic enzymes: The marine planctomycete Rhodopirellula baltica DSM 10527 displays high stereo‐ and enantioselective alkyl sulfatase activity towards (±)‐sec‐alkyl sulfates with retention of configuration through cleavage of their SO bond (see scheme; pathway B), whereas inversion of configurat...

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Veröffentlicht in:	Angewandte Chemie International Edition 2005-10, Vol.44 (39), p.6381-6384
Hauptverfasser:	Wallner, Sabine R., Bauer, Marga, Würdemann, Chris, Wecker, Patricia, Glöckner, Frank O., Faber, Kurt
Format:	Artikel
Sprache:	eng
Schlagworte:	Bacteria - classification Bacteria - enzymology Catalysis enantioselectivity Enzyme Activation Hydrolysis Molecular Structure Planctomycetes Stereoisomerism stereoselectivity sulfatases Sulfatases - chemistry sulfate esters Sulfuric Acid Esters - chemical synthesis Sulfuric Acid Esters - chemistry
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