Polymers of intrinsic microporosity (PIMs): organic materials for membrane separations, heterogeneous catalysis and hydrogen storage
This tutorial review describes recent research directed towards the synthesis of polymer-based organic microporous materials termed Polymers of Intrinsic Microporosity (PIMs). PIMs can be prepared either as insoluble networks or soluble polymers with both types giving solids that exhibit analogous b...
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| Veröffentlicht in: | Chemical Society reviews 2006-01, Vol.35 (8), p.675-683 |
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| container_title | Chemical Society reviews |
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| creator | McKeown, Neil B Budd, Peter M |
| description | This tutorial review describes recent research directed towards the synthesis of polymer-based organic microporous materials termed Polymers of Intrinsic Microporosity (PIMs). PIMs can be prepared either as insoluble networks or soluble polymers with both types giving solids that exhibit analogous behaviour to that of conventional microporous materials such as activated carbons. Soluble PIMs may be processed into thin films for use as highly selective gas separation membranes. Preliminary results also demonstrate the potential of PIMs for heterogeneous catalysis and hydrogen storage. |
| doi_str_mv | 10.1039/b600349d |
| format | Article |
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PIMs can be prepared either as insoluble networks or soluble polymers with both types giving solids that exhibit analogous behaviour to that of conventional microporous materials such as activated carbons. Soluble PIMs may be processed into thin films for use as highly selective gas separation membranes. Preliminary results also demonstrate the potential of PIMs for heterogeneous catalysis and hydrogen storage.</description><subject>Catalysis</subject><subject>Hydrogen - chemistry</subject><subject>Membranes, Artificial</subject><subject>Models, Molecular</subject><subject>Molecular Structure</subject><subject>Organic Chemicals - chemical synthesis</subject><subject>Organic Chemicals - chemistry</subject><subject>Polymers - chemistry</subject><subject>Porosity</subject><subject>Solubility</subject><subject>Surface Properties</subject><issn>0306-0012</issn><issn>1460-4744</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNpFkEtLw0AUhQdRbH2Av0BmJRWMziOZJO5EfEHFLnQdbpM77UiSqXPTRfb-cFNbcXUPnI_D5WPsTIprKXR-MzdC6Div9thYxkZEcRrH-2wstDCREFKN2BHR55BkatQhG0mTGaVMNmbfM1_3DQbi3nLXdsG15EreuDL4lQ-eXNfzyezllS5vuQ8LaDctdBgc1MStD7zBZh6gRU64ggCd8y1d8SUOjF9gi35NvIQO6p4ccWgrvuyr34pT5wMs8IQd2GENT3f3mH08PrzfP0fTt6eX-7tpVGqTdlFqFdpSzVUqIc9ySC0Km1VlInNpk0qBiXObZSrFUprc6lgqbbWBOBVWgE30MbvY7q6C_1ojdUXjqMS6ht8vi8GKSUyiBnCyBQcLRAFtsQqugdAXUhQb48Wf8QE9322u5w1W_-BOsf4BnR1-ag</recordid><startdate>20060101</startdate><enddate>20060101</enddate><creator>McKeown, Neil B</creator><creator>Budd, Peter M</creator><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20060101</creationdate><title>Polymers of intrinsic microporosity (PIMs): organic materials for membrane separations, heterogeneous catalysis and hydrogen storage</title><author>McKeown, Neil B ; Budd, Peter M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c367t-7f2efc2b271a989a7fe0f8dc5191f5d2a649f8827ec169f34123f36a470f0af53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Catalysis</topic><topic>Hydrogen - chemistry</topic><topic>Membranes, Artificial</topic><topic>Models, Molecular</topic><topic>Molecular Structure</topic><topic>Organic Chemicals - chemical synthesis</topic><topic>Organic Chemicals - chemistry</topic><topic>Polymers - chemistry</topic><topic>Porosity</topic><topic>Solubility</topic><topic>Surface Properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>McKeown, Neil B</creatorcontrib><creatorcontrib>Budd, Peter M</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical Society reviews</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>McKeown, Neil B</au><au>Budd, Peter M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polymers of intrinsic microporosity (PIMs): organic materials for membrane separations, heterogeneous catalysis and hydrogen storage</atitle><jtitle>Chemical Society reviews</jtitle><addtitle>Chem Soc Rev</addtitle><date>2006-01-01</date><risdate>2006</risdate><volume>35</volume><issue>8</issue><spage>675</spage><epage>683</epage><pages>675-683</pages><issn>0306-0012</issn><eissn>1460-4744</eissn><abstract>This tutorial review describes recent research directed towards the synthesis of polymer-based organic microporous materials termed Polymers of Intrinsic Microporosity (PIMs). 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| ispartof | Chemical Society reviews, 2006-01, Vol.35 (8), p.675-683 |
| issn | 0306-0012 1460-4744 |
| language | eng |
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| source | Royal Society of Chemistry Journals Archive (1841-2007); MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Catalysis Hydrogen - chemistry Membranes, Artificial Models, Molecular Molecular Structure Organic Chemicals - chemical synthesis Organic Chemicals - chemistry Polymers - chemistry Porosity Solubility Surface Properties |
| title | Polymers of intrinsic microporosity (PIMs): organic materials for membrane separations, heterogeneous catalysis and hydrogen storage |
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