Ruthenium-Catalyzed [1,n]-Metallotropic Shift (n = 3, 5) of Alkynyl Carbene Complex Intermediates
The ruthenium-catalyzed isomerization of diynes and triynes involving propargyl carboxylate moieties affords dienynes and dienediynes, respectively. The [1,n]-metallotropic shift (n = 3, 5) (carbene walk) of in situ generated alkynyl carbene complexes has been proposed for the catalytic isomerizatio...
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| Veröffentlicht in: | Journal of the American Chemical Society 2006-07, Vol.128 (29), p.9270-9271 |
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| container_end_page | 9271 |
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| container_issue | 29 |
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| container_title | Journal of the American Chemical Society |
| container_volume | 128 |
| creator | Ohe, Kouichi Fujita, Michinobu Matsumoto, Hideyuki Tai, Yugo Miki, Koji |
| description | The ruthenium-catalyzed isomerization of diynes and triynes involving propargyl carboxylate moieties affords dienynes and dienediynes, respectively. The [1,n]-metallotropic shift (n = 3, 5) (carbene walk) of in situ generated alkynyl carbene complexes has been proposed for the catalytic isomerization reaction. |
| doi_str_mv | 10.1021/ja0612955 |
| format | Article |
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| source | ACS Publications |
| subjects | Chemistry Exact sciences and technology Kinetics and mechanisms Organic chemistry Reactivity and mechanisms |
| title | Ruthenium-Catalyzed [1,n]-Metallotropic Shift (n = 3, 5) of Alkynyl Carbene Complex Intermediates |
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