Unanticipated formation of ortho-sulfone substituted phenols by anionic thia-Fries rearrangement of (aryl triflate)tricarbonylchromium complexes

Tricarbonylchromium complexes of aryl triflates undergo base-mediated anionic thia-Fries rearrangements to generate push-pull substituted [ortho-hydroxyaryl(trifluoromethylsulfonyl)phenol]tricarbonylchromium complexes under very mild reaction conditions.

Bibliographische Detailangaben

Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2006-01 (28), p.3007-3009
Hauptverfasser:	Zhao, Zhirong, Messinger, Josef, Schön, Uwe, Wartchow, Rudolf, Butenschön, Holger
Format:	Artikel
Sprache:	eng
Schlagworte:	Anions - chemistry Chromium - chemistry Molecular Conformation Molecular Structure Organometallic Compounds - chemistry Phenols - chemical synthesis Phenols - chemistry Sulfones - chemistry
Online-Zugang:	Volltext
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