Echinamines A and B, First Aminated Hydroxynaphthazarins from the Sea Urchin Scaphechinus mirabilis

Two new spinochromes, echinamines A (1) and B (2), were isolated from the sea urchin Scaphechinus mirabilis. Compounds 1 and 2 represent the first examples of natural polyhydroxynaphthazarins with a primary amine group. The structures of 1 and 2 were established by analysis of spectroscopic data and...

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Veröffentlicht in:Journal of natural products (Washington, D.C.) D.C.), 2005-09, Vol.68 (9), p.1390-1393
Hauptverfasser: MISCHENKO, Natalia P., FEDOREYEV, Sergey A., POKHILO, Nataly D., ANUFRIEV, Victor Ph, DENISENKO, Vladimir A., GLAZUNOV, Valery P.
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container_end_page 1393
container_issue 9
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container_title Journal of natural products (Washington, D.C.)
container_volume 68
creator MISCHENKO, Natalia P.
FEDOREYEV, Sergey A.
POKHILO, Nataly D.
ANUFRIEV, Victor Ph
DENISENKO, Vladimir A.
GLAZUNOV, Valery P.
description Two new spinochromes, echinamines A (1) and B (2), were isolated from the sea urchin Scaphechinus mirabilis. Compounds 1 and 2 represent the first examples of natural polyhydroxynaphthazarins with a primary amine group. The structures of 1 and 2 were established by analysis of spectroscopic data and synthesis of their dimethyl ethers.
doi_str_mv 10.1021/np049585r
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source American Chemical Society; MEDLINE
subjects Animals
Biphenyl Compounds
Echinoidea
Japan
Marine
Molecular Structure
Naphthoquinones - chemistry
Naphthoquinones - isolation & purification
Nuclear Magnetic Resonance, Biomolecular
Picrates - pharmacology
Scaphechinus mirabilis
Sea Urchins - chemistry
title Echinamines A and B, First Aminated Hydroxynaphthazarins from the Sea Urchin Scaphechinus mirabilis
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