Spatially Resolved Suzuki Coupling Reaction Initiated and Controlled Using a Catalytic AFM Probe

Spatially Resolved Suzuki Coupling Reaction Initiated and Controlled Using a Catalytic AFM Probe

Appropriately modified proximal probes can be utilized in the spatially resolved chemical coupling of surface-bound and solution-phase reagents. Herein we report a chemically specific Suzuki coupling reaction between a surface-confined aryl bromide and boronic acid reagents in solution achieved usin...

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Veröffentlicht in:Journal of the American Chemical Society 2005-09, Vol.127 (38), p.13082-13083
Hauptverfasser: Davis, Jason J, Coleman, Karl S, Busuttil, Katerina L, Bagshaw, Claire B
Format: Artikel
Sprache:eng
Schlagworte:
Boronic Acids - chemistry
Catalysis
Chemistry
Exact sciences and technology
Hydrocarbons, Brominated - chemical synthesis
Hydrocarbons, Brominated - chemistry
Microscopy, Atomic Force - instrumentation
Microscopy, Atomic Force - methods
Molecular Structure
Nanostructures - chemistry
Organic chemistry
Palladium - chemistry
Surface Properties
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Beschreibung
Zusammenfassung:Appropriately modified proximal probes can be utilized in the spatially resolved chemical coupling of surface-bound and solution-phase reagents. Herein we report a chemically specific Suzuki coupling reaction between a surface-confined aryl bromide and boronic acid reagents in solution achieved using a catalytic AFM probe.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja043235+