Highly Stable Neutral and Positively Charged Dicarbollide Sandwich Complexes

Novel sandwich metallacarboranes commo‐[3,3′‐Ni(8‐SMe2‐1,2‐C2B9H10)2] (1), commo‐[3,3′‐Co(8‐SMe2‐1,2‐C2B9H10)2]+ (2+), commo‐[3,3′‐Ru(8‐SMe2‐1,2‐C2B9H10)2] (4) and commo‐[3,3′‐Fe(8‐SMe2‐1,2‐C2B9H10)2] (5) have been prepared by reaction of [10‐SMe2‐7,8‐nido‐C2B9H10]− with NiCl2⋅6 H2O, CoCl2, [RuCl2(dmso)4] and [FeCl2(dppe)], respectively. Reduction of 2+ with metallic Zn leads to the neutral and isolable complex commo‐[3,3′‐Co(8‐SMe2‐1,2‐C2B9H10)2] (3). Theoretical calculations using the ZINDO/1 semiempirical method show three energy minima for complexes 1–3 and 5 that agree with the presence of three different rotamers in solution at low temperature, while four relative energy minima have been found for 4. The calculated rotational energy barriers for complexes 1–5 have been found in the range 5.2±0.2 and 11.5±0.2 kcal mol−1. These values are in agreement with the experimental data calculated for complexes 2+ and 5. Only one rotamer is found in the X‐ray crystal structure of complexes 1–3, while two are observed for 4. Neutral complexes 1, 3 and 4 exhibit a gauche conformation, whereas a cisoid conformation is found for the 2+ ion. Rotamers evident from X‐ray diffraction studies are in agreement with the global energy minimum calculated by the ZINDO/1 method. The electrochemical studies conducted on 1, 3, 4 and 5 support the proposal that the charge‐compensated ligand [10‐SMe2‐7,8‐nido‐C2B9H10]− stabilises lower oxidation states in metals than the dianionic [7,8‐nido‐C2B9H11]2− and even the [C5H5]− ligands. Cationic cobalt sandwich! The first neutral NiII, CoII, RuII and cationic CoIII sandwich complexes that contain the charge‐compensated [10‐SMe2‐7,8‐nido‐C2B9H10]− ligand, have been successfully prepared (see graphic). All neutral complexes have revealed the unusual gauche or pseudo‐gauche conformation in the solid‐state, while the cationic complex has a cisoid conformation.