Dianhydride-Amine Hydrogen Bonded Perylene Tetracarboxylic Dianhydride and Tetraaminobenzene Rows

Dianhydride-Amine Hydrogen Bonded Perylene Tetracarboxylic Dianhydride and Tetraaminobenzene Rows

We have investigated the coadsorption of perylene tetracarboxylic dianhydride (PTCDA) and tetraaminobenzene (TAB) on the Ag/Si(111)-√3×√3 R30° surface using scanning tunneling microscopy. At room temperature, PTCDA islands with square and herringbone ordering are formed which, on exposure to TAB, ar...

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Veröffentlicht in:The journal of physical chemistry. B 2006-06, Vol.110 (25), p.12207-12210
Hauptverfasser: Ma, J, Rogers, B. L, Humphry, M. J, Ring, D. J, Goretzki, G, Champness, N. R, Beton, P. H
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container_end_page 12210
container_issue 25
container_start_page 12207
container_title The journal of physical chemistry. B
container_volume 110
creator Ma, J
Rogers, B. L
Humphry, M. J
Ring, D. J
Goretzki, G
Champness, N. R
Beton, P. H
description We have investigated the coadsorption of perylene tetracarboxylic dianhydride (PTCDA) and tetraaminobenzene (TAB) on the Ag/Si(111)-√3×√3 R30° surface using scanning tunneling microscopy. At room temperature, PTCDA islands with square and herringbone ordering are formed which, on exposure to TAB, are converted into an intermixed phase in which PTCDA and TAB form alternating rows. From our images, we determine the relative placement of TAB and PTCDA molecules and conclude that the row structure is stabilized by hydrogen bonding between dianhydride and diamine groups. We confirm that this hydrogen bonding junction is stable using ab initio calculations and show that the proposed geometry is consistent with calculated intermolecular dimensions.
doi_str_mv 10.1021/jp057304y
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title Dianhydride-Amine Hydrogen Bonded Perylene Tetracarboxylic Dianhydride and Tetraaminobenzene Rows
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