Self-Assembling Phenylpropyl Ether Dendronized Helical Polyphenylacetylenes

The first example of a self‐assembling phenylpropyl ether based dendronized polymer has been reported and its preferred helical handedness has been determined. Dendronized polymer poly(10) and its nondendritic analogue poly(8) are high‐cis‐content polyphenylacetylenes (PPAs) prepared by using [Rh(nb...

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Veröffentlicht in:	Chemistry : a European journal 2007-01, Vol.13 (34), p.9572-9581
Hauptverfasser:	Percec, Virgil, Peterca, Mihai, Rudick, Jonathan G., Aqad, Emad, Imam, Mohammad R., Heiney, Paul A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetylene - analogs & derivatives Acetylene - chemistry Calorimetry, Differential Scanning Circular Dichroism dendrons helical structures Magnetic Resonance Spectroscopy Models, Molecular Molecular Structure Phenyl Ethers - chemistry polymers Polymers - chemistry self-assembly Solutions Spectrophotometry supramolecular chemistry Temperature X-Ray Diffraction
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