Synthesis and Chemistry of Bridgehead Allylsilanes. Stereoselective Reactions with Aldehydes
A type II intramolecular Diels−Alder reaction provides access to bicyclo[5.3.1] ring systems with an imbedded bridgehead allylsilane. The Lewis acid catalyzed reactions of these compounds with aldehydes proceed efficiently and with control of stereochemistry.
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| Veröffentlicht in: | Organic letters 2005-09, Vol.7 (18), p.3913-3916 |
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| container_title | Organic letters |
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| creator | Lauchli, Ryan Whitney, John M Zhu, Liang Shea, Kenneth J |
| description | A type II intramolecular Diels−Alder reaction provides access to bicyclo[5.3.1] ring systems with an imbedded bridgehead allylsilane. The Lewis acid catalyzed reactions of these compounds with aldehydes proceed efficiently and with control of stereochemistry. |
| doi_str_mv | 10.1021/ol051363c |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1523-7060 |
| ispartof | Organic letters, 2005-09, Vol.7 (18), p.3913-3916 |
| issn | 1523-7060 1523-7052 |
| language | eng |
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| source | MEDLINE; American Chemical Society Journals |
| subjects | Aldehydes - chemistry Catalysis Molecular Structure Silanes - chemical synthesis Silanes - chemistry Stereoisomerism |
| title | Synthesis and Chemistry of Bridgehead Allylsilanes. Stereoselective Reactions with Aldehydes |
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