Highly Efficient Ru−Pseudohalide Catalysts for Olefin Metathesis

Highly Efficient Ru−Pseudohalide Catalysts for Olefin Metathesis

Ruthenium alkylidene complexes containing one aryloxide “pseudohalide” ligand catalyze ring-closing metathesis of diene and ene-yne substrates with exceptionally high efficiency. Chromatographic removal of Ru residues is unexpectedly facile, offering a convenient means of isolating pure organic prod...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of the American Chemical Society 2005-08, Vol.127 (34), p.11882-11883
Hauptverfasser: Conrad, Jay C, Parnas, Henrietta H, Snelgrove, Jennifer L, Fogg, Deryn E
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Exact sciences and technology
Organic chemistry
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 11883
container_issue 34
container_start_page 11882
container_title Journal of the American Chemical Society
container_volume 127
creator Conrad, Jay C
Parnas, Henrietta H
Snelgrove, Jennifer L
Fogg, Deryn E
description Ruthenium alkylidene complexes containing one aryloxide “pseudohalide” ligand catalyze ring-closing metathesis of diene and ene-yne substrates with exceptionally high efficiency. Chromatographic removal of Ru residues is unexpectedly facile, offering a convenient means of isolating pure organic products in high yields.
doi_str_mv 10.1021/ja042736s
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_68511541</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>68511541</sourcerecordid><originalsourceid>FETCH-LOGICAL-a447t-fa38b2c11de9865d6571caf09a89e7ca3b0654a15f59be29985af3fc5c1033da3</originalsourceid><addsrcrecordid>eNpt0M1u00AQB_AVAtFQOPACyBeQOBh29tM-0qgfiFStaLhwWU3Wu2SDY5cdWyJvwJlH5EkwStRcOI1G89Nfoz9jL4G_Ay7g_Qa5ElYaesRmoAUvNQjzmM0456K0lZEn7BnRZlqVqOApOwEDYFWtZuzsKn1bt7viPMbkU-iG4vP459fvWwpj06-xTU0o5jhgu6OBitjn4qYNMXXFdRhwWAdK9Jw9idhSeHGYp-zLxflyflUubi4_zj8sSlTKDmVEWa2EB2hCXRndGG3BY-Q1VnWwHuWKG60QdNT1Koi6rjRGGb32wKVsUJ6yN_vc-9z_GAMNbpvIh7bFLvQjOVNpAK1ggm_30OeeKIfo7nPaYt454O5fYe6hsMm-OoSOq21ojvLQ0AReHwCSxzZm7Hyio7NcKyH55Mq9SzSEnw93zN-dsdJqt7y9cxdfr_Wny8XS3R1z0ZPb9GPupu7-8-BfQVWOkA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>68511541</pqid></control><display><type>article</type><title>Highly Efficient Ru−Pseudohalide Catalysts for Olefin Metathesis</title><source>ACS Publications</source><creator>Conrad, Jay C ; Parnas, Henrietta H ; Snelgrove, Jennifer L ; Fogg, Deryn E</creator><creatorcontrib>Conrad, Jay C ; Parnas, Henrietta H ; Snelgrove, Jennifer L ; Fogg, Deryn E</creatorcontrib><description>Ruthenium alkylidene complexes containing one aryloxide “pseudohalide” ligand catalyze ring-closing metathesis of diene and ene-yne substrates with exceptionally high efficiency. Chromatographic removal of Ru residues is unexpectedly facile, offering a convenient means of isolating pure organic products in high yields.</description><identifier>ISSN: 0002-7863</identifier><identifier>EISSN: 1520-5126</identifier><identifier>DOI: 10.1021/ja042736s</identifier><identifier>PMID: 16117494</identifier><identifier>CODEN: JACSAT</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Chemistry ; Exact sciences and technology ; Organic chemistry</subject><ispartof>Journal of the American Chemical Society, 2005-08, Vol.127 (34), p.11882-11883</ispartof><rights>Copyright © 2005 American Chemical Society</rights><rights>2005 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a447t-fa38b2c11de9865d6571caf09a89e7ca3b0654a15f59be29985af3fc5c1033da3</citedby><cites>FETCH-LOGICAL-a447t-fa38b2c11de9865d6571caf09a89e7ca3b0654a15f59be29985af3fc5c1033da3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ja042736s$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ja042736s$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=17054230$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/16117494$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Conrad, Jay C</creatorcontrib><creatorcontrib>Parnas, Henrietta H</creatorcontrib><creatorcontrib>Snelgrove, Jennifer L</creatorcontrib><creatorcontrib>Fogg, Deryn E</creatorcontrib><title>Highly Efficient Ru−Pseudohalide Catalysts for Olefin Metathesis</title><title>Journal of the American Chemical Society</title><addtitle>J. Am. Chem. Soc</addtitle><description>Ruthenium alkylidene complexes containing one aryloxide “pseudohalide” ligand catalyze ring-closing metathesis of diene and ene-yne substrates with exceptionally high efficiency. Chromatographic removal of Ru residues is unexpectedly facile, offering a convenient means of isolating pure organic products in high yields.</description><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>Organic chemistry</subject><issn>0002-7863</issn><issn>1520-5126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNpt0M1u00AQB_AVAtFQOPACyBeQOBh29tM-0qgfiFStaLhwWU3Wu2SDY5cdWyJvwJlH5EkwStRcOI1G89Nfoz9jL4G_Ay7g_Qa5ElYaesRmoAUvNQjzmM0456K0lZEn7BnRZlqVqOApOwEDYFWtZuzsKn1bt7viPMbkU-iG4vP459fvWwpj06-xTU0o5jhgu6OBitjn4qYNMXXFdRhwWAdK9Jw9idhSeHGYp-zLxflyflUubi4_zj8sSlTKDmVEWa2EB2hCXRndGG3BY-Q1VnWwHuWKG60QdNT1Koi6rjRGGb32wKVsUJ6yN_vc-9z_GAMNbpvIh7bFLvQjOVNpAK1ggm_30OeeKIfo7nPaYt454O5fYe6hsMm-OoSOq21ojvLQ0AReHwCSxzZm7Hyio7NcKyH55Mq9SzSEnw93zN-dsdJqt7y9cxdfr_Wny8XS3R1z0ZPb9GPupu7-8-BfQVWOkA</recordid><startdate>20050831</startdate><enddate>20050831</enddate><creator>Conrad, Jay C</creator><creator>Parnas, Henrietta H</creator><creator>Snelgrove, Jennifer L</creator><creator>Fogg, Deryn E</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20050831</creationdate><title>Highly Efficient Ru−Pseudohalide Catalysts for Olefin Metathesis</title><author>Conrad, Jay C ; Parnas, Henrietta H ; Snelgrove, Jennifer L ; Fogg, Deryn E</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a447t-fa38b2c11de9865d6571caf09a89e7ca3b0654a15f59be29985af3fc5c1033da3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>Organic chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Conrad, Jay C</creatorcontrib><creatorcontrib>Parnas, Henrietta H</creatorcontrib><creatorcontrib>Snelgrove, Jennifer L</creatorcontrib><creatorcontrib>Fogg, Deryn E</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of the American Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Conrad, Jay C</au><au>Parnas, Henrietta H</au><au>Snelgrove, Jennifer L</au><au>Fogg, Deryn E</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Highly Efficient Ru−Pseudohalide Catalysts for Olefin Metathesis</atitle><jtitle>Journal of the American Chemical Society</jtitle><addtitle>J. Am. Chem. Soc</addtitle><date>2005-08-31</date><risdate>2005</risdate><volume>127</volume><issue>34</issue><spage>11882</spage><epage>11883</epage><pages>11882-11883</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><coden>JACSAT</coden><abstract>Ruthenium alkylidene complexes containing one aryloxide “pseudohalide” ligand catalyze ring-closing metathesis of diene and ene-yne substrates with exceptionally high efficiency. Chromatographic removal of Ru residues is unexpectedly facile, offering a convenient means of isolating pure organic products in high yields.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>16117494</pmid><doi>10.1021/ja042736s</doi><tpages>2</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0002-7863
ispartof Journal of the American Chemical Society, 2005-08, Vol.127 (34), p.11882-11883
issn 0002-7863
1520-5126
language eng
recordid cdi_proquest_miscellaneous_68511541
source ACS Publications
subjects Chemistry
Exact sciences and technology
Organic chemistry
title Highly Efficient Ru−Pseudohalide Catalysts for Olefin Metathesis
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-30T22%3A05%3A12IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Highly%20Efficient%20Ru%E2%88%92Pseudohalide%20Catalysts%20for%20Olefin%20Metathesis&rft.jtitle=Journal%20of%20the%20American%20Chemical%20Society&rft.au=Conrad,%20Jay%20C&rft.date=2005-08-31&rft.volume=127&rft.issue=34&rft.spage=11882&rft.epage=11883&rft.pages=11882-11883&rft.issn=0002-7863&rft.eissn=1520-5126&rft.coden=JACSAT&rft_id=info:doi/10.1021/ja042736s&rft_dat=%3Cproquest_cross%3E68511541%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=68511541&rft_id=info:pmid/16117494&rfr_iscdi=true