Complexes of Dibromo(ethylenediamine)- Palladium(II) Observed from Aqueous Solutions by Electrospray Mass Spectrometry

The dimeric complex of dibromo(ethylenediamine)palladium(II) observed in water was investigated using electrospray mass spectrometry. One μM aqueous solutions of Pd(en)Br 2 yielded a variety of previously unreported species. The most abundant ion observed was attributable to the Pd(en)Br 2 · Pd(en)B...

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Veröffentlicht in:	Journal of the American Society for Mass Spectrometry 2005-09, Vol.16 (9), p.1461-1469
Hauptverfasser:	Bach, Stephan B.H., Sepeda, Tiffanee G., Merrill, Grant N., Walmsley, Judith A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Aqueous solutions Chemistry Computer Simulation Coordination compounds Electrospraying Ethylenediamine Ethylenediamines - chemistry Exact sciences and technology Inorganic chemistry and origins of life Ions Isotopes Mass spectrometry Models, Chemical Models, Molecular Molecular Conformation Molecular structure Palladium Palladium - chemistry Preparations and properties Scientific imaging Solutions Solvents - chemistry Spectrometry, Mass, Electrospray Ionization - methods Spectroscopy Water - chemistry
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