The Generation of Neutral Derivatives of Low-Valence Iron, RFe(I), by Netralization—Reionization Mass Spectrometry

The Generation of Neutral Derivatives of Low-Valence Iron, RFe(I), by Netralization—Reionization Mass Spectrometry

Neutralization–reionization mass spectrometry is applied for the generation of low-valence iron derivatives. Neutralization of RFe+ (R = H, F, Cl, Br, I, CN, OH, NH2, acac, C6H5) ions resulted in the corresponding neutrals having lifetimes of at least 5 μs. Atom connectivities in RFe ions and neutra...

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Veröffentlicht in:European journal of mass spectrometry (Chichester, England) England), 2005-01, Vol.11 (3), p.267-275
1. Verfasser: Zagorevskii, Dmitri
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description Neutralization–reionization mass spectrometry is applied for the generation of low-valence iron derivatives. Neutralization of RFe+ (R = H, F, Cl, Br, I, CN, OH, NH2, acac, C6H5) ions resulted in the corresponding neutrals having lifetimes of at least 5 μs. Atom connectivities in RFe ions and neutrals were elucidated by a variety of tandem mass spectrometry techniques. The present study provides the first experimental evidence of the intrinsic stability of neutral IFe, NCFe, acacFe and C6H5Fe.
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title The Generation of Neutral Derivatives of Low-Valence Iron, RFe(I), by Netralization—Reionization Mass Spectrometry
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