Preparation of Iron Amido Complexes via Putative Fe(IV) Imido Intermediates

The isolation and characterization of monomeric Fe(III) amido complexes with hybrid ureate/amidate ligands is described. An aryl azide serves as the source of the amido ligand in preparing the complexes from trigonal monopyramidal Fe(II) precursors. Aryl azides more commonly react with transition me...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Journal of the American Chemical Society 2005-08, Vol.127 (33), p.11596-11597
Hauptverfasser:	Lucas, Robie L, Powell, Douglas R, Borovik, A. S
Format:	Artikel
Sprache:	eng
Schlagworte:	Amides - chemical synthesis Amides - chemistry Chemistry Coordination compounds Crystallography, X-Ray Exact sciences and technology Imides - chemical synthesis Imides - chemistry Inorganic chemistry and origins of life Iron - chemistry Models, Molecular Molecular Conformation Organometallic Compounds - chemical synthesis Preparations and properties Stereoisomerism
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!