Self-Assembly, Binding, and Dynamic Properties of Heterodimeric Porphyrin Macrocycles

A series of heterodimeric tetralactam macrocycles have been self-assembled using two kinetically labile zinc porphyrin-pyridine interactions. The stability constants have been determined by UV−vis titrations in CHCl3. The stability constants depend on the degree of preorganization of the linker unit...

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Veröffentlicht in:	Journal of organic chemistry 2005-08, Vol.70 (17), p.6616-6622
Hauptverfasser:	Ballester, Pablo, Costa, Antoni, Deyà, Pere M, Frontera, Antonio, Gomila, Rosa M, Oliva, Ana I, Sanders, Jeremy K. M, Hunter, Christopher A
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Coordination compounds Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings Inorganic chemistry and origins of life Organic chemistry Preparations and properties
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