A Tetracopper(II)-Tetraradical Cuboidal Core and Its Reactivity as a Functional Model of Phenoxazinone Synthase

The coordination chemistry of the tridentate ligand N-(2-hydroxy-3,5-di-tert-butylphenyl)-2-aminobenzylalcohol H3L has been studied with the copper(II) ion. The ligand is noninnocent in the sense that it is readily oxidized in the presence of air to its o-iminobenzosemiquinonato [L•]2- radical form....

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Veröffentlicht in:	Inorganic chemistry 2007-11, Vol.46 (23), p.9895-9905
Hauptverfasser:	Mukherjee, Chandan, Weyhermüller, Thomas, Bothe, Eberhard, Rentschler, Eva, Chaudhuri, Phalguni
Format:	Artikel
Sprache:	eng
Schlagworte:	Copper - chemistry Crystallography, X-Ray Electrochemistry Magnetic Resonance Spectroscopy Magnetics Models, Molecular Oxidoreductases - chemistry Oxidoreductases - metabolism Spectrometry, Mass, Electrospray Ionization Spectrophotometry, Infrared
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