Surface-Enhanced Raman Scattering from Individual Au Nanoparticles and Nanoparticle Dimer Substrates

Surface-enhanced Raman scattering (SERS) intensities for individual Au nanospheres, nanoshells, and nanosphere and nanoshell dimers coated with nonresonant molecules are measured, where the precise nanoscale geometry of each monomer and dimer is identified through in situ atomic force microscopy. Th...

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Veröffentlicht in:Nano letters 2005-08, Vol.5 (8), p.1569-1574
Hauptverfasser: Talley, Chad E, Jackson, Joseph B, Oubre, Chris, Grady, Nathaniel K, Hollars, Christopher W, Lane, Stephen M, Huser, Thomas R, Nordlander, Peter, Halas, Naomi J
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container_end_page 1574
container_issue 8
container_start_page 1569
container_title Nano letters
container_volume 5
creator Talley, Chad E
Jackson, Joseph B
Oubre, Chris
Grady, Nathaniel K
Hollars, Christopher W
Lane, Stephen M
Huser, Thomas R
Nordlander, Peter
Halas, Naomi J
description Surface-enhanced Raman scattering (SERS) intensities for individual Au nanospheres, nanoshells, and nanosphere and nanoshell dimers coated with nonresonant molecules are measured, where the precise nanoscale geometry of each monomer and dimer is identified through in situ atomic force microscopy. The observed intensities correlate with the integrated quartic local electromagnetic field calculated for each specific nanostructure geometry. In this study, we find that suitably fabricated nanoshells can provide SERS enhancements comparable to nanosphere dimers.
doi_str_mv 10.1021/nl050928v
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source MEDLINE; American Chemical Society Journals
subjects Applied sciences
Condensed matter: structure, mechanical and thermal properties
Dimerization
Electronics
Exact sciences and technology
Gold - analysis
Gold - chemistry
Materials Testing - methods
Microelectronic fabrication (materials and surfaces technology)
Microscopy, Atomic Force
Nanoscale materials: clusters, nanoparticles, nanotubes, and nanocrystals
Nanostructures - chemistry
Nanostructures - ultrastructure
Particle Size
Physics
Scattering, Radiation
Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices
Spectrum Analysis, Raman - methods
Structure of solids and liquids
crystallography
Surface Properties
title Surface-Enhanced Raman Scattering from Individual Au Nanoparticles and Nanoparticle Dimer Substrates
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