Hydrocarbon-Soluble Calcium Hydride: A "Worker-Bee" in Calcium Chemistry

The reactivity of the hydrocarbon‐soluble calcium hydride complex [{CaH(dipp‐nacnac)(thf)}2] (1; dipp‐nacnac=CH{(CMe)(2,6‐iPr2C6H3N)}2) with a large variety of substrates has been investigated. Addition of 1 to CO and CN functionalities gave easy access to calcium alkoxide and amide complexes. Sim...

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Veröffentlicht in:	Chemistry : a European journal 2007-11, Vol.13 (32), p.8928-8938
Hauptverfasser:	Spielmann, Jan, Harder, Sjoerd
Format:	Artikel
Sprache:	eng
Schlagworte:	alkaline-earth metals calcium Calcium - chemistry Crystallography, X-Ray Hydrocarbons - chemistry metal hydrides Models, Molecular Molecular Conformation Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry reduction Solubility Stereoisomerism
Online-Zugang:	Volltext
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