General Ruthenium-Catalyzed Synthesis of Aromatic Amines

Simple as that: The synthesis of aromatic amines from aliphatic amines proceeds under transfer hydrogenation conditions (see scheme). By applying the Shvo catalyst, general applicability is shown in the conversion of a variety of functionalized anilines and aliphatic amines. This base‐ and salt‐free...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie (International ed.) 2007-01, Vol.46 (43), p.8291-8294
Hauptverfasser: Hollmann, Dirk, Bähn, Sebastian, Tillack, Annegret, Beller, Matthias
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 8294
container_issue 43
container_start_page 8291
container_title Angewandte Chemie (International ed.)
container_volume 46
creator Hollmann, Dirk
Bähn, Sebastian
Tillack, Annegret
Beller, Matthias
description Simple as that: The synthesis of aromatic amines from aliphatic amines proceeds under transfer hydrogenation conditions (see scheme). By applying the Shvo catalyst, general applicability is shown in the conversion of a variety of functionalized anilines and aliphatic amines. This base‐ and salt‐free method can be an excellent alternative to the known synthesis of anilines.
doi_str_mv 10.1002/anie.200703119
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_68448577</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>68448577</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4719-bb6d737aa1c35107971620fbe8316018bab4c997dc3a929908a058dc4a05fc693</originalsourceid><addsrcrecordid>eNqFkDtP7DAQRi0EAu5CSwmp6LKM48SPchVgQTzFQ5SW4zhgyAPsRNzl12OUFdBRzWh0vk-ag9AOhikGSA5Ua800AWBAMBYraBNnCY4JY2Q17CkhMeMZ3kD_vH8OPOdA19EGZlwApbCJ-Ny0xqk6uhn6J9PaoYlz1at68WHK6HbRhqO3PuqqaOa6RvVWR7PGtsZvobVK1d5sL-cE3R8f3eUn8fnV_DSfncc6ZVjERUFLRphSWJMMAxMM0wSqwnCCKWBeqCLVQrBSEyUSIYAryHip0zAqTQWZoP2x99V1b4PxvWys16auVWu6wUvK05Rn4d8Jmo6gdp33zlTy1dlGuYXEIL9cyS9X8ttVCOwum4eiMeUPvpQTADEC77Y2iz_q5Ozy9Oh3eTxmre_N_--sci-SBh-ZfLicy_zsMLnIxYW8DvzeyFeqk-rRWS_vbxPABIAnhPCUfAITCYzD</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>68448577</pqid></control><display><type>article</type><title>General Ruthenium-Catalyzed Synthesis of Aromatic Amines</title><source>MEDLINE</source><source>Access via Wiley Online Library</source><creator>Hollmann, Dirk ; Bähn, Sebastian ; Tillack, Annegret ; Beller, Matthias</creator><creatorcontrib>Hollmann, Dirk ; Bähn, Sebastian ; Tillack, Annegret ; Beller, Matthias</creatorcontrib><description>Simple as that: The synthesis of aromatic amines from aliphatic amines proceeds under transfer hydrogenation conditions (see scheme). By applying the Shvo catalyst, general applicability is shown in the conversion of a variety of functionalized anilines and aliphatic amines. This base‐ and salt‐free method can be an excellent alternative to the known synthesis of anilines.</description><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.200703119</identifier><identifier>PMID: 17890660</identifier><language>eng</language><publisher>Weinheim: Wiley-VCH Verlag</publisher><subject>Alkylation ; aminations ; Amines - chemical synthesis ; aniline ; Catalysis ; homogeneous catalysis ; Hydrogen - chemistry ; ruthenium ; Ruthenium - chemistry ; Shvo catalyst</subject><ispartof>Angewandte Chemie (International ed.), 2007-01, Vol.46 (43), p.8291-8294</ispartof><rights>Copyright © 2007 WILEY‐VCH Verlag GmbH &amp; Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4719-bb6d737aa1c35107971620fbe8316018bab4c997dc3a929908a058dc4a05fc693</citedby><cites>FETCH-LOGICAL-c4719-bb6d737aa1c35107971620fbe8316018bab4c997dc3a929908a058dc4a05fc693</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.200703119$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.200703119$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/17890660$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Hollmann, Dirk</creatorcontrib><creatorcontrib>Bähn, Sebastian</creatorcontrib><creatorcontrib>Tillack, Annegret</creatorcontrib><creatorcontrib>Beller, Matthias</creatorcontrib><title>General Ruthenium-Catalyzed Synthesis of Aromatic Amines</title><title>Angewandte Chemie (International ed.)</title><addtitle>Angewandte Chemie International Edition</addtitle><description>Simple as that: The synthesis of aromatic amines from aliphatic amines proceeds under transfer hydrogenation conditions (see scheme). By applying the Shvo catalyst, general applicability is shown in the conversion of a variety of functionalized anilines and aliphatic amines. This base‐ and salt‐free method can be an excellent alternative to the known synthesis of anilines.</description><subject>Alkylation</subject><subject>aminations</subject><subject>Amines - chemical synthesis</subject><subject>aniline</subject><subject>Catalysis</subject><subject>homogeneous catalysis</subject><subject>Hydrogen - chemistry</subject><subject>ruthenium</subject><subject>Ruthenium - chemistry</subject><subject>Shvo catalyst</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkDtP7DAQRi0EAu5CSwmp6LKM48SPchVgQTzFQ5SW4zhgyAPsRNzl12OUFdBRzWh0vk-ag9AOhikGSA5Ua800AWBAMBYraBNnCY4JY2Q17CkhMeMZ3kD_vH8OPOdA19EGZlwApbCJ-Ny0xqk6uhn6J9PaoYlz1at68WHK6HbRhqO3PuqqaOa6RvVWR7PGtsZvobVK1d5sL-cE3R8f3eUn8fnV_DSfncc6ZVjERUFLRphSWJMMAxMM0wSqwnCCKWBeqCLVQrBSEyUSIYAryHip0zAqTQWZoP2x99V1b4PxvWys16auVWu6wUvK05Rn4d8Jmo6gdp33zlTy1dlGuYXEIL9cyS9X8ttVCOwum4eiMeUPvpQTADEC77Y2iz_q5Ozy9Oh3eTxmre_N_--sci-SBh-ZfLicy_zsMLnIxYW8DvzeyFeqk-rRWS_vbxPABIAnhPCUfAITCYzD</recordid><startdate>20070101</startdate><enddate>20070101</enddate><creator>Hollmann, Dirk</creator><creator>Bähn, Sebastian</creator><creator>Tillack, Annegret</creator><creator>Beller, Matthias</creator><general>Wiley-VCH Verlag</general><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>FBQ</scope><scope>BSCLL</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20070101</creationdate><title>General Ruthenium-Catalyzed Synthesis of Aromatic Amines</title><author>Hollmann, Dirk ; Bähn, Sebastian ; Tillack, Annegret ; Beller, Matthias</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4719-bb6d737aa1c35107971620fbe8316018bab4c997dc3a929908a058dc4a05fc693</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Alkylation</topic><topic>aminations</topic><topic>Amines - chemical synthesis</topic><topic>aniline</topic><topic>Catalysis</topic><topic>homogeneous catalysis</topic><topic>Hydrogen - chemistry</topic><topic>ruthenium</topic><topic>Ruthenium - chemistry</topic><topic>Shvo catalyst</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hollmann, Dirk</creatorcontrib><creatorcontrib>Bähn, Sebastian</creatorcontrib><creatorcontrib>Tillack, Annegret</creatorcontrib><creatorcontrib>Beller, Matthias</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie (International ed.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hollmann, Dirk</au><au>Bähn, Sebastian</au><au>Tillack, Annegret</au><au>Beller, Matthias</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>General Ruthenium-Catalyzed Synthesis of Aromatic Amines</atitle><jtitle>Angewandte Chemie (International ed.)</jtitle><addtitle>Angewandte Chemie International Edition</addtitle><date>2007-01-01</date><risdate>2007</risdate><volume>46</volume><issue>43</issue><spage>8291</spage><epage>8294</epage><pages>8291-8294</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>Simple as that: The synthesis of aromatic amines from aliphatic amines proceeds under transfer hydrogenation conditions (see scheme). By applying the Shvo catalyst, general applicability is shown in the conversion of a variety of functionalized anilines and aliphatic amines. This base‐ and salt‐free method can be an excellent alternative to the known synthesis of anilines.</abstract><cop>Weinheim</cop><pub>Wiley-VCH Verlag</pub><pmid>17890660</pmid><doi>10.1002/anie.200703119</doi><tpages>4</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1433-7851
ispartof Angewandte Chemie (International ed.), 2007-01, Vol.46 (43), p.8291-8294
issn 1433-7851
1521-3773
language eng
recordid cdi_proquest_miscellaneous_68448577
source MEDLINE; Access via Wiley Online Library
subjects Alkylation
aminations
Amines - chemical synthesis
aniline
Catalysis
homogeneous catalysis
Hydrogen - chemistry
ruthenium
Ruthenium - chemistry
Shvo catalyst
title General Ruthenium-Catalyzed Synthesis of Aromatic Amines
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-03T20%3A59%3A24IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=General%20Ruthenium-Catalyzed%20Synthesis%20of%20Aromatic%20Amines&rft.jtitle=Angewandte%20Chemie%20(International%20ed.)&rft.au=Hollmann,%20Dirk&rft.date=2007-01-01&rft.volume=46&rft.issue=43&rft.spage=8291&rft.epage=8294&rft.pages=8291-8294&rft.issn=1433-7851&rft.eissn=1521-3773&rft_id=info:doi/10.1002/anie.200703119&rft_dat=%3Cproquest_cross%3E68448577%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=68448577&rft_id=info:pmid/17890660&rfr_iscdi=true