General Ruthenium-Catalyzed Synthesis of Aromatic Amines
Simple as that: The synthesis of aromatic amines from aliphatic amines proceeds under transfer hydrogenation conditions (see scheme). By applying the Shvo catalyst, general applicability is shown in the conversion of a variety of functionalized anilines and aliphatic amines. This base‐ and salt‐free...
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Veröffentlicht in: | Angewandte Chemie (International ed.) 2007-01, Vol.46 (43), p.8291-8294 |
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creator | Hollmann, Dirk Bähn, Sebastian Tillack, Annegret Beller, Matthias |
description | Simple as that: The synthesis of aromatic amines from aliphatic amines proceeds under transfer hydrogenation conditions (see scheme). By applying the Shvo catalyst, general applicability is shown in the conversion of a variety of functionalized anilines and aliphatic amines. This base‐ and salt‐free method can be an excellent alternative to the known synthesis of anilines. |
doi_str_mv | 10.1002/anie.200703119 |
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By applying the Shvo catalyst, general applicability is shown in the conversion of a variety of functionalized anilines and aliphatic amines. This base‐ and salt‐free method can be an excellent alternative to the known synthesis of anilines.</description><subject>Alkylation</subject><subject>aminations</subject><subject>Amines - chemical synthesis</subject><subject>aniline</subject><subject>Catalysis</subject><subject>homogeneous catalysis</subject><subject>Hydrogen - chemistry</subject><subject>ruthenium</subject><subject>Ruthenium - chemistry</subject><subject>Shvo catalyst</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkDtP7DAQRi0EAu5CSwmp6LKM48SPchVgQTzFQ5SW4zhgyAPsRNzl12OUFdBRzWh0vk-ag9AOhikGSA5Ua800AWBAMBYraBNnCY4JY2Q17CkhMeMZ3kD_vH8OPOdA19EGZlwApbCJ-Ny0xqk6uhn6J9PaoYlz1at68WHK6HbRhqO3PuqqaOa6RvVWR7PGtsZvobVK1d5sL-cE3R8f3eUn8fnV_DSfncc6ZVjERUFLRphSWJMMAxMM0wSqwnCCKWBeqCLVQrBSEyUSIYAryHip0zAqTQWZoP2x99V1b4PxvWys16auVWu6wUvK05Rn4d8Jmo6gdp33zlTy1dlGuYXEIL9cyS9X8ttVCOwum4eiMeUPvpQTADEC77Y2iz_q5Ozy9Oh3eTxmre_N_--sci-SBh-ZfLicy_zsMLnIxYW8DvzeyFeqk-rRWS_vbxPABIAnhPCUfAITCYzD</recordid><startdate>20070101</startdate><enddate>20070101</enddate><creator>Hollmann, Dirk</creator><creator>Bähn, Sebastian</creator><creator>Tillack, Annegret</creator><creator>Beller, Matthias</creator><general>Wiley-VCH Verlag</general><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>FBQ</scope><scope>BSCLL</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20070101</creationdate><title>General Ruthenium-Catalyzed Synthesis of Aromatic Amines</title><author>Hollmann, Dirk ; Bähn, Sebastian ; Tillack, Annegret ; Beller, Matthias</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4719-bb6d737aa1c35107971620fbe8316018bab4c997dc3a929908a058dc4a05fc693</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Alkylation</topic><topic>aminations</topic><topic>Amines - chemical synthesis</topic><topic>aniline</topic><topic>Catalysis</topic><topic>homogeneous catalysis</topic><topic>Hydrogen - chemistry</topic><topic>ruthenium</topic><topic>Ruthenium - chemistry</topic><topic>Shvo catalyst</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hollmann, Dirk</creatorcontrib><creatorcontrib>Bähn, Sebastian</creatorcontrib><creatorcontrib>Tillack, Annegret</creatorcontrib><creatorcontrib>Beller, Matthias</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie (International ed.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hollmann, Dirk</au><au>Bähn, Sebastian</au><au>Tillack, Annegret</au><au>Beller, Matthias</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>General Ruthenium-Catalyzed Synthesis of Aromatic Amines</atitle><jtitle>Angewandte Chemie (International ed.)</jtitle><addtitle>Angewandte Chemie International Edition</addtitle><date>2007-01-01</date><risdate>2007</risdate><volume>46</volume><issue>43</issue><spage>8291</spage><epage>8294</epage><pages>8291-8294</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>Simple as that: The synthesis of aromatic amines from aliphatic amines proceeds under transfer hydrogenation conditions (see scheme). By applying the Shvo catalyst, general applicability is shown in the conversion of a variety of functionalized anilines and aliphatic amines. This base‐ and salt‐free method can be an excellent alternative to the known synthesis of anilines.</abstract><cop>Weinheim</cop><pub>Wiley-VCH Verlag</pub><pmid>17890660</pmid><doi>10.1002/anie.200703119</doi><tpages>4</tpages></addata></record> |
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subjects | Alkylation aminations Amines - chemical synthesis aniline Catalysis homogeneous catalysis Hydrogen - chemistry ruthenium Ruthenium - chemistry Shvo catalyst |
title | General Ruthenium-Catalyzed Synthesis of Aromatic Amines |
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