General Ruthenium-Catalyzed Synthesis of Aromatic Amines

General Ruthenium-Catalyzed Synthesis of Aromatic Amines

Simple as that: The synthesis of aromatic amines from aliphatic amines proceeds under transfer hydrogenation conditions (see scheme). By applying the Shvo catalyst, general applicability is shown in the conversion of a variety of functionalized anilines and aliphatic amines. This base‐ and salt‐free...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie (International ed.) 2007-01, Vol.46 (43), p.8291-8294
Hauptverfasser: Hollmann, Dirk, Bähn, Sebastian, Tillack, Annegret, Beller, Matthias
Format: Artikel
Sprache:eng
Schlagworte:
Alkylation
aminations
Amines - chemical synthesis
aniline
Catalysis
homogeneous catalysis
Hydrogen - chemistry
ruthenium
Ruthenium - chemistry
Shvo catalyst
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Simple as that: The synthesis of aromatic amines from aliphatic amines proceeds under transfer hydrogenation conditions (see scheme). By applying the Shvo catalyst, general applicability is shown in the conversion of a variety of functionalized anilines and aliphatic amines. This base‐ and salt‐free method can be an excellent alternative to the known synthesis of anilines.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200703119