Multiple nitrene insertions into metal-sulfur bonds of dithiocarbamate complexes: synthesis of sulfido-amido and zwitterionic tetraamido complexes

The iodine(III) reagent, PhI[double bond, length as m-dash]NTs, acts as a source of the nitrene fragment NTs, which undergoes facile insertion into the metal-sulfur bonds of a range of dithiocarbamate complexes. Addition of two equivalents of PhI=NTs to [M(S(2)CNR2)2] affords sulfido-amido complexes...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2005-08 (16), p.2688-2695
Hauptverfasser:	Hogarth, Graeme, Holman, K Travis, Pateman, Andrew, Sella, Andrea, Steed, Jonathan W, Richards, Idris
Format:	Artikel
Sprache:	eng
Schlagworte:	Amides - chemistry Cobalt - chemistry Copper - chemistry Crystallography, X-Ray Imines - chemistry Metals, Heavy - chemistry Models, Molecular Molecular Conformation Nickel - chemistry Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Stereoisomerism Sulfur - chemistry Thiocarbamates - chemistry
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