Direct observation of the unstable intermediates in radical addition reaction by using an interfacing microchip combined with an NMR

Direct observation of the unstable intermediate in the radical addition reaction of the oxime ether 1 mediated by triethylborane (Et3B) is described using 1H and 11B micro channeled cell for synthesis monitoring (MICCS), which was recently developed as an interfacing microchip for NMR. It was possib...

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Veröffentlicht in:	Magnetic resonance in chemistry 2007-11, Vol.45 (11), p.989-992
Hauptverfasser:	Nakakoshi, Masamichi, Ueda, Masafumi, Sakurai, Satoshi, Asakura, K., Utsumi, Hiroshi, Miyata, Okiko, Naito, Takeaki, Takahashi, Yutaka
Format:	Artikel
Sprache:	eng
Schlagworte:	11B Boranes - chemistry Boron - analysis Et3B intermediate Magnetic Resonance Spectroscopy - instrumentation Magnetic Resonance Spectroscopy - methods MIcro channeled cell for synthesis monitoring Nuclear magnetic resonance oxime ether Oximes - chemistry Protons radical reaction
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