Investigation of the gas phase reactivity of the 1-adamantyl radical using a distonic radical anion approach

The gas phase reactions of the bridgehead 3-carboxylato-1-adamantyl radical anion were observed with a series of neutral reagents using a modified electrospray ionisation linear ion trap mass spectrometer. This distonic radical anion was observed to undergo processes suggestive of radical reactivity...

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Veröffentlicht in:Organic & biomolecular chemistry 2007-01, Vol.5 (21), p.3495-3503
Hauptverfasser: Harman, David G, Blanksby, Stephen J
Format: Artikel
Sprache:eng
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