Bis(acesulfamato-kappaO4)diaquabis(3-methylpyridine-kappaN)nickel(II)
In the crystal structure of the title compound [systematic name: diaquabis(6-methyl-2,2-dioxo-1,2,3-oxathiazin-4-olato-kappaO4)bis(3-methylpyridine-kappaN)nickel(II)], [Ni(C4H4NO4S)2(C6H7N)2(H2O)2], the Ni(II) centre resides on a centre of symmetry and has a distorted octahedral geometry. The basal...
Gespeichert in:
| Veröffentlicht in: | Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2007-01, Vol.63 (Pt 1), p.m13-m15 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | m15 |
|---|---|
| container_issue | Pt 1 |
| container_start_page | m13 |
| container_title | Acta crystallographica. Section C, Crystal structure communications |
| container_volume | 63 |
| creator | Dege, Necmi Içbudak, Hasan Adiyaman, Elif |
| description | In the crystal structure of the title compound [systematic name: diaquabis(6-methyl-2,2-dioxo-1,2,3-oxathiazin-4-olato-kappaO4)bis(3-methylpyridine-kappaN)nickel(II)], [Ni(C4H4NO4S)2(C6H7N)2(H2O)2], the Ni(II) centre resides on a centre of symmetry and has a distorted octahedral geometry. The basal plane is formed by two carbonyl O atoms of two monodentate trans-oriented acesulfamate ligands and two trans aqua ligands. The axial positions in the octahedron are occupied by two N atoms of two trans pyridine ligands. Molecules are stacked in columns running along the a axis. There are pi-pi stacking interactions between the molecules in each column, with a distance of 3.623 (2) A between the centroids of the pyridine rings. There are also O-H...O interactions between the columns. |
| doi_str_mv | 10.1107/S0108270106050591 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_68405279</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>68405279</sourcerecordid><originalsourceid>FETCH-LOGICAL-c299t-7e4cd4863a568b30ffb6c3d254adac24d9d917329b73826b28a4581a0fc4ad683</originalsourceid><addsrcrecordid>eNplkLtOw0AURLcAkRD4ABpKlBSGfT9KiAJEikgB1Nb17lossWPHaxf--ziKJQqae6WZM1MMQncEPxKC1dMnJlhTNVyJBRaGXKDpSUpO2gRdx_iLMaaUsis0IYoOGBNTtHoJcQ7Wx67IoYS2SnZQ17DlCxfg0EE22CwpffvTF3XfBBf2_ox8LPbB7nwxX68XN-gyhyL62_HP0Pfr6mv5nmy2b-vl8yax1Jg2UZ5bx7VkIKTOGM7zTFrmqODgwFLujDNEMWoyxTSVGdXAhSaAczsQUrMZejj31k116Hxs0zJE64sC9r7qYio1x4IqM4DkDNqmirHxeVo3oYSmTwlOT3ul__YaMvdjeZeV3v0lxrHYEVxkZnE</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>68405279</pqid></control><display><type>article</type><title>Bis(acesulfamato-kappaO4)diaquabis(3-methylpyridine-kappaN)nickel(II)</title><source>Wiley Online Library - AutoHoldings Journals</source><source>MEDLINE</source><source>Alma/SFX Local Collection</source><creator>Dege, Necmi ; Içbudak, Hasan ; Adiyaman, Elif</creator><creatorcontrib>Dege, Necmi ; Içbudak, Hasan ; Adiyaman, Elif</creatorcontrib><description>In the crystal structure of the title compound [systematic name: diaquabis(6-methyl-2,2-dioxo-1,2,3-oxathiazin-4-olato-kappaO4)bis(3-methylpyridine-kappaN)nickel(II)], [Ni(C4H4NO4S)2(C6H7N)2(H2O)2], the Ni(II) centre resides on a centre of symmetry and has a distorted octahedral geometry. The basal plane is formed by two carbonyl O atoms of two monodentate trans-oriented acesulfamate ligands and two trans aqua ligands. The axial positions in the octahedron are occupied by two N atoms of two trans pyridine ligands. Molecules are stacked in columns running along the a axis. There are pi-pi stacking interactions between the molecules in each column, with a distance of 3.623 (2) A between the centroids of the pyridine rings. There are also O-H...O interactions between the columns.</description><identifier>ISSN: 0108-2701</identifier><identifier>DOI: 10.1107/S0108270106050591</identifier><identifier>PMID: 17206035</identifier><language>eng</language><publisher>United States</publisher><subject>Crystallography, X-Ray ; Hydrogen Bonding ; Models, Molecular ; Molecular Conformation ; Nickel - chemistry ; Organometallic Compounds - chemistry</subject><ispartof>Acta crystallographica. Section C, Crystal structure communications, 2007-01, Vol.63 (Pt 1), p.m13-m15</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c299t-7e4cd4863a568b30ffb6c3d254adac24d9d917329b73826b28a4581a0fc4ad683</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/17206035$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Dege, Necmi</creatorcontrib><creatorcontrib>Içbudak, Hasan</creatorcontrib><creatorcontrib>Adiyaman, Elif</creatorcontrib><title>Bis(acesulfamato-kappaO4)diaquabis(3-methylpyridine-kappaN)nickel(II)</title><title>Acta crystallographica. Section C, Crystal structure communications</title><addtitle>Acta Crystallogr C</addtitle><description>In the crystal structure of the title compound [systematic name: diaquabis(6-methyl-2,2-dioxo-1,2,3-oxathiazin-4-olato-kappaO4)bis(3-methylpyridine-kappaN)nickel(II)], [Ni(C4H4NO4S)2(C6H7N)2(H2O)2], the Ni(II) centre resides on a centre of symmetry and has a distorted octahedral geometry. The basal plane is formed by two carbonyl O atoms of two monodentate trans-oriented acesulfamate ligands and two trans aqua ligands. The axial positions in the octahedron are occupied by two N atoms of two trans pyridine ligands. Molecules are stacked in columns running along the a axis. There are pi-pi stacking interactions between the molecules in each column, with a distance of 3.623 (2) A between the centroids of the pyridine rings. There are also O-H...O interactions between the columns.</description><subject>Crystallography, X-Ray</subject><subject>Hydrogen Bonding</subject><subject>Models, Molecular</subject><subject>Molecular Conformation</subject><subject>Nickel - chemistry</subject><subject>Organometallic Compounds - chemistry</subject><issn>0108-2701</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNplkLtOw0AURLcAkRD4ABpKlBSGfT9KiAJEikgB1Nb17lossWPHaxf--ziKJQqae6WZM1MMQncEPxKC1dMnJlhTNVyJBRaGXKDpSUpO2gRdx_iLMaaUsis0IYoOGBNTtHoJcQ7Wx67IoYS2SnZQ17DlCxfg0EE22CwpffvTF3XfBBf2_ox8LPbB7nwxX68XN-gyhyL62_HP0Pfr6mv5nmy2b-vl8yax1Jg2UZ5bx7VkIKTOGM7zTFrmqODgwFLujDNEMWoyxTSVGdXAhSaAczsQUrMZejj31k116Hxs0zJE64sC9r7qYio1x4IqM4DkDNqmirHxeVo3oYSmTwlOT3ul__YaMvdjeZeV3v0lxrHYEVxkZnE</recordid><startdate>20070101</startdate><enddate>20070101</enddate><creator>Dege, Necmi</creator><creator>Içbudak, Hasan</creator><creator>Adiyaman, Elif</creator><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20070101</creationdate><title>Bis(acesulfamato-kappaO4)diaquabis(3-methylpyridine-kappaN)nickel(II)</title><author>Dege, Necmi ; Içbudak, Hasan ; Adiyaman, Elif</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c299t-7e4cd4863a568b30ffb6c3d254adac24d9d917329b73826b28a4581a0fc4ad683</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Crystallography, X-Ray</topic><topic>Hydrogen Bonding</topic><topic>Models, Molecular</topic><topic>Molecular Conformation</topic><topic>Nickel - chemistry</topic><topic>Organometallic Compounds - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dege, Necmi</creatorcontrib><creatorcontrib>Içbudak, Hasan</creatorcontrib><creatorcontrib>Adiyaman, Elif</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Acta crystallographica. Section C, Crystal structure communications</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dege, Necmi</au><au>Içbudak, Hasan</au><au>Adiyaman, Elif</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Bis(acesulfamato-kappaO4)diaquabis(3-methylpyridine-kappaN)nickel(II)</atitle><jtitle>Acta crystallographica. Section C, Crystal structure communications</jtitle><addtitle>Acta Crystallogr C</addtitle><date>2007-01-01</date><risdate>2007</risdate><volume>63</volume><issue>Pt 1</issue><spage>m13</spage><epage>m15</epage><pages>m13-m15</pages><issn>0108-2701</issn><abstract>In the crystal structure of the title compound [systematic name: diaquabis(6-methyl-2,2-dioxo-1,2,3-oxathiazin-4-olato-kappaO4)bis(3-methylpyridine-kappaN)nickel(II)], [Ni(C4H4NO4S)2(C6H7N)2(H2O)2], the Ni(II) centre resides on a centre of symmetry and has a distorted octahedral geometry. The basal plane is formed by two carbonyl O atoms of two monodentate trans-oriented acesulfamate ligands and two trans aqua ligands. The axial positions in the octahedron are occupied by two N atoms of two trans pyridine ligands. Molecules are stacked in columns running along the a axis. There are pi-pi stacking interactions between the molecules in each column, with a distance of 3.623 (2) A between the centroids of the pyridine rings. There are also O-H...O interactions between the columns.</abstract><cop>United States</cop><pmid>17206035</pmid><doi>10.1107/S0108270106050591</doi></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0108-2701 |
| ispartof | Acta crystallographica. Section C, Crystal structure communications, 2007-01, Vol.63 (Pt 1), p.m13-m15 |
| issn | 0108-2701 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_68405279 |
| source | Wiley Online Library - AutoHoldings Journals; MEDLINE; Alma/SFX Local Collection |
| subjects | Crystallography, X-Ray Hydrogen Bonding Models, Molecular Molecular Conformation Nickel - chemistry Organometallic Compounds - chemistry |
| title | Bis(acesulfamato-kappaO4)diaquabis(3-methylpyridine-kappaN)nickel(II) |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-19T09%3A06%3A33IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Bis(acesulfamato-kappaO4)diaquabis(3-methylpyridine-kappaN)nickel(II)&rft.jtitle=Acta%20crystallographica.%20Section%20C,%20Crystal%20structure%20communications&rft.au=Dege,%20Necmi&rft.date=2007-01-01&rft.volume=63&rft.issue=Pt%201&rft.spage=m13&rft.epage=m15&rft.pages=m13-m15&rft.issn=0108-2701&rft_id=info:doi/10.1107/S0108270106050591&rft_dat=%3Cproquest_cross%3E68405279%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=68405279&rft_id=info:pmid/17206035&rfr_iscdi=true |