Zirconocene-Mediated Highly Regio- and Stereoselective Synthesis of Multisubstituted Olefins Starting from 1-Alkynylboronates

Multisubstituted olefins are efficiently prepared by the zirconocene-mediated regio- and stereoselective coupling between 1-alkynylboronates and ethylene, followed by sequential transformation in moderate to high yields. The proper combination of substrates and reaction conditions is important for h...

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Veröffentlicht in:	Journal of the American Chemical Society 2007-10, Vol.129 (42), p.12634-12635
Hauptverfasser:	Nishihara, Yasushi, Miyasaka, Mitsuru, Okamoto, Masanori, Takahashi, Hideki, Inoue, Eiji, Tanemura, Kenki, Takagi, Kentaro
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes - chemical synthesis Alkenes - chemistry Boron - chemistry Chemistry, Organic - methods Chemistry, Pharmaceutical - methods Models, Chemical Molecular Conformation Organometallic Compounds - chemistry Stereoisomerism Tamoxifen - chemical synthesis Zirconium - chemistry
Online-Zugang:	Volltext
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