Preparation and characterization of mixed-ligand cobalt(III) complexes containing (3-aminopropyl)dimethylphosphine (pdmp). Conformation of the six-membered pdmp chelate ring

Several new cobalt(III) complexes containing (3-aminopropyl)dimethylphosphine (pdmp) have been prepared, and their molecular structures have been determined. A dichloro complex of trans(Cl,Cl)-cis(P,P)-[CoCl(2)(pdmp)(2)]PF(6) (1) was prepared from trans-[CoCl(2)(py)(4)]Cl.6H(2)O and pdmp. X-Ray crys...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2007-01 (3), p.308-319
Hauptverfasser:	Suzuki, Takayoshi, Fujiiwara, Katsuhiro, Takagi, Hideo D, Kashiwabara, Kazuo
Format:	Artikel
Sprache:	eng
Schlagworte:	Chelating Agents - chemistry Cobalt - chemistry Ligands Models, Molecular Molecular Conformation Organometallic Compounds - chemistry X-Ray Diffraction
Online-Zugang:	Volltext
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