Laser Microprobe with Fourier Transform Ion Cyclotron Resonance Mass Spectrometer for Surface Analysis
Fourier transform ion cyclotron resonance laser microprobe mass spectrometry (FTICR LMMS) uses focused laser irradiation of solids with a spot of 5 μm and a FTICR mass analyzer for local analysis with high mass resolution. A new ion source design has been developed to improve the extraction and tran...
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| Veröffentlicht in: | Analytical chemistry (Washington) 2007-01, Vol.79 (1), p.280-290 |
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| creator | Moisio, Harri Vaeck, Luc Van Vangaever, Frank |
| description | Fourier transform ion cyclotron resonance laser microprobe mass spectrometry (FTICR LMMS) uses focused laser irradiation of solids with a spot of 5 μm and a FTICR mass analyzer for local analysis with high mass resolution. A new ion source design has been developed to improve the extraction and transfer of ions generated in an external laser microprobe source. Calculations predicted trapping of ions initially emitted with angles up to 40° and 60° from the surface and from a distance of 1 mm above the sample, respectively. The analytical performances of the method have been verified on two sets of test samples. First, detection of chemisorbed benzotriazole on copper, average of two monolayers, has been shown with less sample consumption than typically required in static secondary ion mass spectrometry with a time-of-flight analyzer. Second, experiments on a thermal plate for offset printing have shown the feasibility of analysis and quantification of dyes embedded in a polymer matrix. |
| doi_str_mv | 10.1021/ac0612776 |
| format | Article |
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Second, experiments on a thermal plate for offset printing have shown the feasibility of analysis and quantification of dyes embedded in a polymer matrix.</description><subject>Analytical chemistry</subject><subject>Chemistry</subject><subject>Dyes</subject><subject>Exact sciences and technology</subject><subject>Feasibility</subject><subject>Fourier transforms</subject><subject>Mass spectrometry</subject><subject>Polymers</subject><subject>Spectrometric and optical methods</subject><issn>0003-2700</issn><issn>1520-6882</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNpl0F1rVDEQBuAgit1WL_wDchAseHF0JknzcVkWWwtblO6KlyGbTfDU87HNnIPuvzdlly7oVULmyTDzMvYG4SMCx08-gEKutXrGZnjBoVbG8OdsBgCi5hrghJ0S3QMgAqqX7AQ1WlnkjKWFp5ir2ybkYZuHdax-N-PP6mqYclPeV9n3lIbcVTdDX813oR3GXG53kYbe9yFWt56oWm5jKO9dHMufwqvllJMv1cvetztq6BV7kXxL8fXhPGPfrz6v5l_qxdfrm_nlovZS2rEWCpLcaCmVWAfFdVksaiPEJpqgDedBWhuNlKgSt-jtOgaeAP3GpyhDsOKMne_7ll0epkij6xoKsW19H4eJnDLCoART4Lt_4H1ZuUxLjqM2Rmv-iD7sUQmHKMfktrnpfN45BPeYvHtKvti3h4bTuoubozxEXcD7A_AUfJtKsqGhozMSrbFQXL13DY3xz1Pd519OaaEv3Orb0qG6E3D9Q7jFsa8PdFzi_wH_Auq5pWo</recordid><startdate>20070101</startdate><enddate>20070101</enddate><creator>Moisio, Harri</creator><creator>Vaeck, Luc Van</creator><creator>Vangaever, Frank</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7TA</scope><scope>7TB</scope><scope>7TM</scope><scope>7U5</scope><scope>7U7</scope><scope>7U9</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>H94</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope><scope>7X8</scope></search><sort><creationdate>20070101</creationdate><title>Laser Microprobe with Fourier Transform Ion Cyclotron Resonance Mass Spectrometer for Surface Analysis</title><author>Moisio, Harri ; Vaeck, Luc Van ; Vangaever, Frank</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a449t-360f4d74463bc627ac0e7833de8c7822c499e84416f291a9bec2f01adafe4cc93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Analytical chemistry</topic><topic>Chemistry</topic><topic>Dyes</topic><topic>Exact sciences and technology</topic><topic>Feasibility</topic><topic>Fourier transforms</topic><topic>Mass spectrometry</topic><topic>Polymers</topic><topic>Spectrometric and optical methods</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Moisio, Harri</creatorcontrib><creatorcontrib>Vaeck, Luc Van</creatorcontrib><creatorcontrib>Vangaever, Frank</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Nucleic Acids Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Toxicology Abstracts</collection><collection>Virology and AIDS Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>AIDS and Cancer Research Abstracts</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Analytical chemistry (Washington)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Moisio, Harri</au><au>Vaeck, Luc Van</au><au>Vangaever, Frank</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Laser Microprobe with Fourier Transform Ion Cyclotron Resonance Mass Spectrometer for Surface Analysis</atitle><jtitle>Analytical chemistry (Washington)</jtitle><addtitle>Anal. 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| source | ACS Publications |
| subjects | Analytical chemistry Chemistry Dyes Exact sciences and technology Feasibility Fourier transforms Mass spectrometry Polymers Spectrometric and optical methods |
| title | Laser Microprobe with Fourier Transform Ion Cyclotron Resonance Mass Spectrometer for Surface Analysis |
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