Selective Gas Sorption within a Dynamic Metal-Organic Framework

Selective Gas Sorption within a Dynamic Metal-Organic Framework

A microporous metal-organic framework 1 Co(NDC)(4,4‘-Bipy)0.5·G x (NDC = 2,6-naphthalenedicarboxylate; 4,4‘-Bipy = 4,4‘-bipyridine; G = guest molecules) was synthesized and structurally characterized of a doubly interpenetrated primitive cubic net. To make use of the framework flexibility, 1 was act...

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Veröffentlicht in:Inorganic chemistry 2007-10, Vol.46 (21), p.8705-8709
Hauptverfasser: Chen, Banglin, Ma, Shengqian, Hurtado, Eric J, Lobkovsky, Emil B, Liang, Chengdu, Zhu, Haoguo, Dai, Sheng
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container_end_page 8709
container_issue 21
container_start_page 8705
container_title Inorganic chemistry
container_volume 46
creator Chen, Banglin
Ma, Shengqian
Hurtado, Eric J
Lobkovsky, Emil B
Liang, Chengdu
Zhu, Haoguo
Dai, Sheng
description A microporous metal-organic framework 1 Co(NDC)(4,4‘-Bipy)0.5·G x (NDC = 2,6-naphthalenedicarboxylate; 4,4‘-Bipy = 4,4‘-bipyridine; G = guest molecules) was synthesized and structurally characterized of a doubly interpenetrated primitive cubic net. To make use of the framework flexibility, 1 was activated at temperatures of 150 and 200 °C to form 1a and 1b, respectively, exhibiting highly selective sorption behaviors of hydrogen over nitrogen-gas molecules.
doi_str_mv 10.1021/ic7013573
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