Ammonium Boranes for the Selective Complexation of Cyanide or Fluoride Ions in Water

With the recognition of aqueous fluoride and cyanide ions as an objective, we have investigated the anion binding properties of two isomeric ammonium boranes, namely [p-(Mes2B)C6H4(NMe3)]+ ([1]+) and [o-(Mes2B)C6H4(NMe3)]+ ([2]+). These cationic boranes, which could be obtained by reaction of the kn...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Journal of the American Chemical Society 2007-10, Vol.129 (39), p.11978-11986
Hauptverfasser:	Hudnall, Todd W, Gabbaï, François P
Format:	Artikel
Sprache:	eng
Schlagworte:	Anions - chemistry Boranes - chemical synthesis Boranes - chemistry Crystallography, X-Ray Cyanides - chemistry Fluorides - chemistry Kinetics Magnetic Resonance Spectroscopy Methanol - chemistry Models, Molecular Quaternary Ammonium Compounds - chemical synthesis Quaternary Ammonium Compounds - chemistry Solvents - chemistry Water - chemistry
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!