Metal−Porphyrin Orbital Interactions in Highly Saddled Low-Spin Iron(III) Porphyrin Complexes

Substituent effects of the meso-aryl (Ar) groups on the 1H and 13C NMR chemical shifts in a series of low-spin highly saddled iron(III) octaethyltetraarylporphyrinates, [Fe(OETArP)L2]+, where axial ligands (L) are imidazole (HIm) and tert-butylisocyanide ( t BuNC), have been examined to reveal the n...

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Veröffentlicht in:	Inorganic chemistry 2007-10, Vol.46 (20), p.8193-8207
Hauptverfasser:	Ohgo, Yoshiki, Hoshino, Akito, Okamura, Tomoya, Uekusa, Hidehiro, Hashizume, Daisuke, Ikezaki, Akira, Nakamura, Mikio
Format:	Artikel
Sprache:	eng
Schlagworte:	Crystallography, X-Ray Electron Spin Resonance Spectroscopy Iron - chemistry Magnetic Resonance Spectroscopy Metals - chemistry Models, Molecular Porphyrins - chemistry Spectrophotometry, Ultraviolet
Online-Zugang:	Volltext
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