Unusual fragmentation of CH2Cl2 by an Ir(III) centre bonded to a doubly metalated Tp(Ms) Ligand (Tp(Ms) = hydrotris(3-mesitylpyrazol-1-yl)borate)

Unusual fragmentation of CH2Cl2 by an Ir(III) centre bonded to a doubly metalated Tp(Ms) Ligand (Tp(Ms) = hydrotris(3-mesitylpyrazol-1-yl)borate)

The Ir(III) compound Tp(Ms'')Ir(N2), that contains a pentadentate, doubly metalated 3-mesityl substituted tris(pyrazolyl)borate ligand, induces the cleavage of C-H and C-Cl bonds of CH2Cl2 to yield a highly electrophilic chlorocarbene Ir=C(H)Cl complex.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2006-10 (37), p.3921-3923
Hauptverfasser: López, Jorge A, Mereiter, Kurt, Paneque, Margarita, Poveda, Manuel L, Serrano, Oracio, Trofimenko, Swiatoslaw, Carmona, Ernesto
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container_issue 37
container_start_page 3921
container_title Chemical communications (Cambridge, England)
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creator López, Jorge A
Mereiter, Kurt
Paneque, Margarita
Poveda, Manuel L
Serrano, Oracio
Trofimenko, Swiatoslaw
Carmona, Ernesto
description The Ir(III) compound Tp(Ms'')Ir(N2), that contains a pentadentate, doubly metalated 3-mesityl substituted tris(pyrazolyl)borate ligand, induces the cleavage of C-H and C-Cl bonds of CH2Cl2 to yield a highly electrophilic chlorocarbene Ir=C(H)Cl complex.
doi_str_mv 10.1039/b608293a
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source Royal Society of Chemistry Journals Archive (1841-2007); Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
title Unusual fragmentation of CH2Cl2 by an Ir(III) centre bonded to a doubly metalated Tp(Ms) Ligand (Tp(Ms) = hydrotris(3-mesitylpyrazol-1-yl)borate)
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